Fe(AsO4): A new iron(iii) arsenate synthesized from thermal treatment of (NH4)[Fe(AsO4)F]
Literature Information
Begoña Bazán, José L. Mesa, José L. Pizarro, Andrés T. Aguayo, María I. Arriortua, Teófilo Rojo
The new orthorhombic Fe(AsO4) phase has been synthesized by thermal treatment at 525 °C of a new (NH4)[Fe(AsO4)F] compound, with a [Fe(AsO4)F]− skeleton showing channels where the ammonium cations are located. The crystal structure of Fe(AsO4) has been solved from single-crystal data. The structure is formed by layers of edge-sharing dimeric octahedra, and interconnected by chains of alternating FeO6 octahedra and AsO4 tetrahedra.
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