Fe(AsO4): A new iron(iii) arsenate synthesized from thermal treatment of (NH4)[Fe(AsO4)F]

Literature Information

Publication Date 2003-02-06
DOI 10.1039/B210998K
Impact Factor 6.222
Authors

Begoña Bazán, José L. Mesa, José L. Pizarro, Andrés T. Aguayo, María I. Arriortua, Teófilo Rojo


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Abstract

The new orthorhombic Fe(AsO4) phase has been synthesized by thermal treatment at 525 °C of a new (NH4)[Fe(AsO4)F] compound, with a [Fe(AsO4)F]− skeleton showing channels where the ammonium cations are located. The crystal structure of Fe(AsO4) has been solved from single-crystal data. The structure is formed by layers of edge-sharing dimeric octahedra, and interconnected by chains of alternating FeO6 octahedra and AsO4 tetrahedra.

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