Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin

Literature Information

Publication Date 2003-01-28
DOI 10.1039/B210645K
Impact Factor 6.222
Authors

Tat-Shing Lai, Stephen K. S. Lee, Lam-Lung Yeung, Hai-Yang Liu, Ian D. Williams, Chi K. Chang


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Abstract

With a highly encumbered manganese porphyrin as catalyst, significant improvements in regioselectivity towards less substituted C–C double bond in diene epoxidation were attained by simply adding organic bases as axial ligand.

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