Nucleophilic substitution of alkylchlorodihydro[60]fullerenes: thermodynamic stabilities of alkylated C60cation intermediates

Literature Information

Publication Date 2002-11-20
DOI 10.1039/B210126B
Impact Factor 6.222
Authors

Toshikazu Kitagawa, Yangsoo Lee, Masaaki Hanamura, Harumi Sakamoto, Hirofumi Konno, Ken’ichi Takeuchi, Koichi Komatsu


View Original

Abstract

Thermodynamic stabilities of alkylated C60 cations (RC60+) were determined based on the activation free energies of SN1 solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation.

Related Literature

Theoretical and experimental studies of substitution of cadmium into hydroxyapatite

J. Terra, G. B. Gonzalez, A. M. Rossi, J. G. Eon, D. E. Ellis

2010-10-25 Paper

DOI: 10.1039/C0CP01032D

A study of alcohol-induced gelation of β-lactoglobulin with small-angle neutron scattering, neutron spin echo, and dynamic light scattering measurements

Koji Yoshida, Toshio Yamaguchi, Noboru Osaka, Hitoshi Endo, Mitsuhiro Shibayama

2010-02-11 Paper

DOI: 10.1039/B920187D

Making gold nanoparticles fluorescent for simultaneous absorption and fluorescence detection on the single particle level

Alexander Gaiduk, Paul V. Ruijgrok, Mustafa Yorulmaz, Michel Orrit

2010-11-01 Paper

DOI: 10.1039/C0CP01389G

High-resolution solid-state 13C μMAS NMR with long coherence life times

Suresh K. Vasa, Hans Janssen, Ernst R. H. Van Eck, Arno P. M. Kentgens

2010-11-12 Communication

DOI: 10.1039/C0CP01929A

ZnO-based dye solar cell with pure ionic-liquid electrolyte and organic sensitizer: the relevance of the dye–oxide interaction in an ionic-liquid medium

E. Guillén, J. Idígoras, T. Berger, J. A. Anta, C. Fernández-Lorenzo, R. Alcántara, J. Navas, J. Martín-Calleja

2010-10-26 Paper

DOI: 10.1039/C0CP00507J

Formation dynamics and nature of tryptophan's primary photoproduct in aqueous solution

J. Léonard, D. Sharma, B. Szafarowicz, K. Torgasin, S. Haacke

2010-08-16 Paper

DOI: 10.1039/C0CP00615G

Ionic liquid silver salt complexes for propene/propane separation

Friederike Agel, Fee Pitsch, Florian Felix Krull, Peter Schulz, Matthias Wessling, Thomas Melin, Peter Wasserscheid

2010-11-04 Paper

DOI: 10.1039/C0CP01104E

Manipulating the growth of aqueous semiconductor nanocrystals through amine-promoted kinetic process

Jishu Han, Hao Zhang, Ding Zhou, Bai Yang

2009-11-07 Communication

DOI: 10.1039/B919655B

Back matter

Front/Back Matter

DOI: 10.1039/C0CP90144J

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.