Nucleophilic substitution of alkylchlorodihydro[60]fullerenes: thermodynamic stabilities of alkylated C60cation intermediates
Literature Information
Toshikazu Kitagawa, Yangsoo Lee, Masaaki Hanamura, Harumi Sakamoto, Hirofumi Konno, Ken’ichi Takeuchi, Koichi Komatsu
Thermodynamic stabilities of alkylated C60 cations (RC60+) were determined based on the activation free energies of SN1 solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation.
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