BIS(I-PROPYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
CAS Number:
12130-65-3
Molecular Formula:
C16H22Cl2Ti
Vinyl-λ3-iodanes act as efficient sulfur atom acceptors: vinylic SN2-based strategy for conversion of tertiary thioamides to amides
Literature Information
Publication Date
2002-10-24
DOI
10.1039/B209097J
Impact Factor
6.222
Authors
Masahito Ochiai, Shinji Yamamoto
View Original
Abstract
Exposure of tertiary thioamides to (E)-1-hexenyl(phenyl)-λ3-iodane results in vinylic SN2 reaction to give the inverted (Z)-S-vinylthioimidonium salts, which under alkaline hydrolysis (Na2CO3 or K2CO3) selectively afford amides, while (Z)-S-vinyl thioesters are obtained in high yields via the hydrolysis under acidic conditions (HCl).
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Recommended Compounds
![1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure](https://static.chemtradehub.com/structs/115/1159822-71-5-0320.webp "1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure")
1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride
CAS Number:
1159822-71-5
Molecular Formula:
C14H22Cl2N2
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