A cyclic hexacopper(ii) fluoro complex that encapsulates two fluoride anions

Literature Information

Publication Date 2002-11-08
DOI 10.1039/B207923M
Impact Factor 6.222
Authors

Xiaoming Liu, Abbie C. McLaughlin, Marcelo P. de Miranda, Eric J. L. McInnes, Colin A. Kilner, Malcolm A. Halcrow


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Abstract

The complex [{Cu3(HpztBu)4(μ-pztBu)2(μ-F)2(μ3-F)}2]F2 (HpztBu = 3{5}-tert-butylpyrazole) has a cyclic, C2v-symmetric hexacopper core. The two non-coordinated F− anions are encapsulated within cavities formed by three HpztBu ligands.

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