ATEM-EELS study of new diamond-like phases in the B–C–N system

Literature Information

Publication Date 2002-09-17
DOI 10.1039/B206691B
Impact Factor 3.676
Authors

Vladimir L. Solozhenko


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Abstract

Novel ternary diamond-like phases of the B–C–N system were synthesized at pressures up to 30 GPa and temperatures up to 3500 K by static and dynamic compression of graphite-like BN–C solid solutions. The structure and properties of these new phases were studied using analytical transmission electron microscopy (ATEM), electron energy loss spectroscopy (EELS) and powder X-ray diffraction. Our results reveal that B, C and N atoms are homogeneously distributed over the crystal lattices of the B–C–N phases under study without forming superstructures. All ternary diamond-like B–C–N phases indicate a clear tendency to decompose at high temperatures because of supersaturation of diamond in the BN component.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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