Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water + ethanol)
Literature Information
Vesna Najdanovic-Visak, José M. S. S. Esperança, Luís P. N. Rebelo, Manuel Nunes da Ponte, Henrique J. R. Guedes, Kenneth R. Seddon, Jerzy Szydlowski
A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.
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