Laser spectroscopy of 1,2,3,4-tetrahydro-1-naphthol·ROH (R = H, CH3) clusters

Literature Information

Publication Date 2002-05-16
DOI 10.1039/B201347A
Impact Factor 3.676
Authors

A. Paladini, M. Satta, D. Catone, A. Filippi, S. Piccirillo, M. Speranza


View Original

Abstract

Wavelength and mass selected resonant enhanced multi-photon ionization (REMPI) spectroscopy is an excellent tool for characterising molecular clusters. Mass selected resonant two photon ionisation (R2PI) spectra of the S1 ← S0 transition of 1,2,3,4-tetrahydro-1-naphthol (TR) and their complexes with solvent molecules such as water (W) and methanol (MeOH) have been recorded after a supersonic molecular beam expansion. Spectra have been analysed with the aid of ab initio molecular orbital calculations conducted at the B3LYP/6-31G** level of the theory.

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