NMR studies of the molecular dynamics of tert-butyl chloride confined in the mesoporous molecular sieve MCM-41

Literature Information

Publication Date 2002-04-30
DOI 10.1039/B200634K
Impact Factor 3.676
Authors

Lidia Wasyluk, Barbara Peplinska, Stefan Jurga


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Abstract

The molecular dynamics of tert-butyl chloride (TBC) confined in the molecular sieve MCM-41 were investigated by measuring NMR linewidths, lineshapes, and 1H and 2H spin–lattice relaxation times. The temperatures of phase transitions of confined TBC are different from those in bulk. The behaviour of confined TBC can be explained assuming that the guest molecules form two kinds of molecular layers, one located at the pore surface and the other at the centre of the pore.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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