Kinetics of gas phase reactions of OH and Cl with aromatic aldehydes
Literature Information
Rate constants for the OH and Cl reactions with four aromatic aldehydes have been determined at 298 ± 2 K and atmospheric pressure using a relative rate method. The measured rate constants are (in cm3 molecule−1 s−1): kOHkClBenzaldehyde(1.2 ± 0.2) × 10−11(10 ± 1) × 10−11o-Tolualdehyde(1.8 ± 0.2) × 10−11(19 ± 2) × 10−11m-Tolualdehyde(1.7 ± 0.2) × 10−11(17 ± 2) × 10−11p-Tolualdehyde(1.3 ± 0.2) × 10−11(14 ± 2) × 10−11 This work provides the first measurements for the OH and Cl reaction rate constants with tolualdehydes. The results obtained are presented and compared with the previous measurements only available for benzaldehyde. The atmospheric implications are also discussed.
Related Literature
Thermal hysteresis of Morin transition in hematite particles
L. Suber, P. Imperatori, A. Mari, G. Marchegiani, M. Vasquez Mansilla, D. Fiorani, W. R. Plunkett, D. Rinaldi, C. Cannas, G. Ennas
DOI: 10.1039/B925371H
On the different roles of anions and cations in the solvation of enzymes in ionic liquids
Marco Klähn, Geraldine S. Lim, Abirami Seduraman, Ping Wu
DOI: 10.1039/C0CP01509A
Characterization and mechanism study of micrometer-sized secondary assembly of β-cyclodextrin
Yifeng He, Xinghai Shen, Qingde Chen, Hongcheng Gao
DOI: 10.1039/C0CP00899K
Rotational dynamics of positively and negatively charged solutes in ionic liquid and viscous molecular solvent studied by time-resolved fluorescence anisotropy measurements
Dinesh Chandra Khara, Anunay Samanta
DOI: 10.1039/B925099A
Solvatochromic shifts of single-walled carbon nanotubes in nonpolar microenvironments
Carlos A. Silvera-Batista, Randy K. Wang, Philip Weinberg
DOI: 10.1039/B927053A
Multimodal coupling of optical transitions and plasmonic oscillations in rhodamine B modified gold nanoparticles
Magdalena Stobiecka, Maria Hepel
DOI: 10.1039/C0CP00553C
In vitro hydrogen production—using energy from the sun
Henning Krassen, Sascha Ott, Joachim Heberle
DOI: 10.1039/C0CP01163K
A novel stabilisation model for rutheniumnanoparticles in imidazolium ionic liquids: in situ spectroscopic and labelling evidence
Paul S. Campbell, Catherine C. Santini, Denis Bouchu, Bernard Fenet, Karine Philippot, Bruno Chaudret, Agílio A. H. Pádua, Yves Chauvin
DOI: 10.1039/B925329G
A natural missing link between activated and downhill protein folding scenarios
Feng Liu, Caroline Maynard, Gregory Scott, Artem Melnykov, Kathleen B. Hall
DOI: 10.1039/B925033F
Self-organized distribution of periodicity and chaos in an electrochemical oscillator
Melke A. Nascimento, Hamilton Varela
DOI: 10.1039/C0CP01038C
You might also like
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure 2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure](https://static.chemtradehub.com/structs/308/3089-17-6-750b.webp)
