LIF study of the reactions of the IO radical with NO and NO2 over an extended range of temperature and pressure

Literature Information

Publication Date 2002-04-10
DOI 10.1039/B110084J
Impact Factor 3.676
Authors


View Original

Abstract

A pulsed laser-photolysis / pulsed laser induced fluorescence technique was used to investigate the kinetics of the reactions of the IO radical with NO and NO2. For the reaction (1) IO + NO → I + NO2 the rate constants between 233 and 346 K were found to be kIO+NO(T) = (4.3 ± 1.0) × 10−12exp[(397 ± 65) K/T] cm3 s−1, independent of pressure between 13 and 130 mbar as measured at 286 K. Reaction (2) IO + NO2 + M → IONO2 + M has been studied between 48 and 402 mbar in the temperature range 238–298 K. The rate constants were found to be in the fall-off region between second- and third-order kinetics for this pressure range. Assuming a broadening factor of FC = 0.6, independent of temperature, a set of fall-off parameters with k0(T) = 4.1 × 10−31 (T/298 K)−6.3 cm6 s−1 and k∞ = 1.0 × 10−11 cm3 s−1 was found to adequately describe the data.

Related Literature

Selective oxidation of dimethyl ether to methyl formate over trifunctional MoO3–SnO2catalyst under mild conditions

Qingde Zhang, Yizhuo Han, Yisheng Tan

2013-03-19 Communication

DOI: 10.1039/C3GC40279G

Application of multivariate statistics in assessment of green analytical chemistry parameters of analytical methodologies

Marek Tobiszewski, Stefan Tsakovski, Vasil Simeonov, Jacek Namieśnik

2013-04-03 Paper

DOI: 10.1039/C3GC36976E

Front cover

Cover

DOI: 10.1039/C3GC90022C

Mesoporous molecular sieves K2O/Ba(Ca or Mg)-MCM-41 with base sites as heterogeneous catalysts for the production of liquid hydrocarbonfuel from catalytic cracking of rubber seed oil

Lu Li, Kejing Quan, Junming Xu, Fusheng Liu, Shiwei Liu, Shitao Yu, Congxia Xie, Baoquan Zhang, Xiaoping Ge

2013-07-12 Paper

DOI: 10.1039/C3GC40796A

Highly efficient iron(0) nanoparticle-catalyzed hydrogenation in water in flow

Go Hamasaka, Takao Osako, Yoichi M. A. Yamada, Chao-Jun Li, Audrey Moores

2013-06-27 Paper

DOI: 10.1039/C3GC40789F

Cellulose-derived superparamagnetic carbonaceous solid acid catalyst for cellulose hydrolysis in an ionic liquid or aqueous reaction system

Haixin Guo, Youfen Lian, Lulu Yan, Xinhua Qi, Richard Lee Smith, Jr.

2013-05-14 Paper

DOI: 10.1039/C3GC40433A

Photocatalysis on supported gold and silver nanoparticles under ultraviolet and visible light irradiation

Sarina Sarina, Eric R. Waclawik, Huaiyong Zhu

2013-05-10 Tutorial Review

DOI: 10.1039/C3GC40450A

Benzylic hydroxylation of aromatic compounds by P450 BM3

Katharina Neufeld, Jan Marienhagen, Ulrich Schwaneberg

2013-07-08 Paper

DOI: 10.1039/C3GC40838H

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.