From degeneration to damping of electrochemical oscillation induced by temperature controlling of heat-compensation type

Literature Information

Publication Date 2002-02-19
DOI 10.1039/B108572G
Impact Factor 3.676
Authors

Jinglei Lei, Jiuli Luo


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Abstract

Instead of the passivation of the electrode surface, another approach leading to the nonsustaining character of electrochemical oscillation induced by temperature control of heat-compensation type is suggested in this paper. As an illustration the thermokinetic behavior of the anodic dissolution of copper in acidic chloride solution influenced by both the chemical reaction–heat conduction coupling and the temperature undulation in the controlling error range has been analyzed quantitatively. It turned out that this kind of temperature fluctuation will lead to limit cycle type degeneration of the sustained electrode chemical oscillation. As a result, two kinds of evolutionary perspectives, both the quasi-periodic oscillation and the damping oscillation, are expected.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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