From degeneration to damping of electrochemical oscillation induced by temperature controlling of heat-compensation type
Literature Information
Jinglei Lei, Jiuli Luo
Instead of the passivation of the electrode surface, another approach leading to the nonsustaining character of electrochemical oscillation induced by temperature control of heat-compensation type is suggested in this paper. As an illustration the thermokinetic behavior of the anodic dissolution of copper in acidic chloride solution influenced by both the chemical reaction–heat conduction coupling and the temperature undulation in the controlling error range has been analyzed quantitatively. It turned out that this kind of temperature fluctuation will lead to limit cycle type degeneration of the sustained electrode chemical oscillation. As a result, two kinds of evolutionary perspectives, both the quasi-periodic oscillation and the damping oscillation, are expected.
Recommended Journals
Related Literature
3D-printed zeolite monoliths with hierarchical porosity for selective methanol to light olefin reaction
Xin Li, Fateme Rezaei, Ali A. Rownaghi
DOI: 10.1039/C8RE00095F
“Pushing and pulling” the equilibrium through bubble mediated reactive separation for ethyl acetate production
Fahed Javed, Zufishan Shamair, Shahzad Ali, Ainy Hafeez, Tahir Fazal, William B. Zimmerman, Fahad Rehman
DOI: 10.1039/C8RE00328A
In situ formation of crosslinked core–corona polymeric nanoparticles from a novel hyperbranched core
Yu Zheng, Kristofer J. Thurecht, Xinyong Chen, Clive J. Roberts, Steven M. Howdle, Wenxin Wang
DOI: 10.1039/C2PY20247F
A comprehensive chemical model for the preliminary steps of the thermal stabilization process in a carbon fibre manufacturing line
Khashayar Badii, Gelayol Golkarnarenji, Abbas S. Milani, Hamid Khayyam
DOI: 10.1039/C8RE00164B
Copper(0)-mediated radical polymerisation in a self-generating biphasic system
Cyrille Boyer, Amir Atme, Christopher Waldron, Athina Anastasaki, Paul Wilson, Per B. Zetterlund, David Haddleton, Michael R. Whittaker
DOI: 10.1039/C2PY20560B
A statistical approach dealing with multicollinearity among predictors in microfluidic reactor operation to control liquid-phase oxidation selectivity
Kaushik Sivaramakrishnan, Yucheng Wu, Arno de Klerk, Neda Nazemifard
DOI: 10.1039/C8RE00134K
Base-free, tunable, Au-catalyzed oxidative esterification of alcohols in continuous flow
Felicity J. Roberts, Christian Richard, Fessehaye W. Zemichael, King Kuok (Mimi) Hii, Klaus Hellgardt, Colin Brennan, David A. Sale
DOI: 10.1039/C8RE00085A
Tailoring the multiphase flow pattern of gas and liquid through micro-packed bed of pillars
Nathalie Márquez, Jacob A. Moulijn, Michiel Makkee, Michiel T. Kreutzer, Pedro Castaño
DOI: 10.1039/C9RE00056A
pH and enzymatic double-stimuli responsive multi-compartment micelles from supra-amphiphilic polymers
Chao Wang, Yuetong Kang, Kai Liu, Zhibo Li, Zhiqiang Wang, Xi Zhang
DOI: 10.1039/C2PY20334K
You might also like
What regulatory guidelines apply to 6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1)?
6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1) falls under various...
Are there alternatives to 1-Pyrrolidineethanol, β-methyl-α-phenyl-, (αS,βR) (CAS: 123620-80-4) in synthesis?
While there are no direct alternatives, similar compounds like 1-Pyrrolidineetha...
Is 4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) safe?
4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) is ...
How should 2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) be stored?
2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) should be stored in a...
What are the physical and chemical properties of 4,5,6,7-Tetrahydro-1H-indazole hydrochloride (CAS: 18161-11-0)?
4,5,6,7-Tetrahydro-1H-indazole hydrochloride is a white crystalline solid with a...
What is (2R)-1-Methoxy-3-phenyl-2-propanamine (CAS: 59919-07-2)?
(2R)-1-Methoxy-3-phenyl-2-propanamine is a chiral organic compound with the CAS ...
What industries use Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate (CAS: 56649-47-9)?
Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate is used in various industries...
What regulatory guidelines apply to 4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3)?
4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3) falls...
What industries use (S)-3-Amino-5-phenylpentanoic acid hydrochloride (CAS: 331846-97-0)?
(S)-3-Amino-5-phenylpentanoic acid hydrochloride is primarily used in the pharma...
How is 7-methoxy-1-benzothiophene-2-carboxylic acid (CAS: 88791-07-5) typically synthesized?
7-Methoxy-1-benzothiophene-2-carboxylic acid is typically synthesized by reactin...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














