Apparent and partial ideal molar isentropic compressibilities of binary liquid mixtures
Literature Information
Michael I. Davis, Gérard Douhéret, João Carlos R. Reis, Michael J. Blandamer
The excess apparent molar isentropic compressibilities of binary liquid mixtures, which are derived from ultrasonic speed measurements, are frequently used to probe the macroscopic effects of intermolecular forces. The composition dependence of the apparent and partial molar isentropic compressibilities of components of ideal mixtures is explored, with special interest being shown in the infinite aqueous dilution limit. Attention is also paid to convenient methods for estimating the effects of solvation and of cosphere overlap in water-rich mixtures. In particular, it is shown that the difference between excess partial molar and excess apparent molar isentropic compressibilities gives a strong indication of the magnitudes of the effects of solute–solute interactions.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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