Apparent and partial ideal molar isentropic compressibilities of binary liquid mixtures

Literature Information

Publication Date 2001-09-21
DOI 10.1039/B104974G
Impact Factor 3.676
Authors

Michael I. Davis, Gérard Douhéret, João Carlos R. Reis, Michael J. Blandamer


View Original

Abstract

The excess apparent molar isentropic compressibilities of binary liquid mixtures, which are derived from ultrasonic speed measurements, are frequently used to probe the macroscopic effects of intermolecular forces. The composition dependence of the apparent and partial molar isentropic compressibilities of components of ideal mixtures is explored, with special interest being shown in the infinite aqueous dilution limit. Attention is also paid to convenient methods for estimating the effects of solvation and of cosphere overlap in water-rich mixtures. In particular, it is shown that the difference between excess partial molar and excess apparent molar isentropic compressibilities gives a strong indication of the magnitudes of the effects of solute–solute interactions.

Related Literature

Two-mode dynamics in dispersed systems: the case of particle-stabilized foams studied by diffusing wave spectroscopy

Antonio Stocco, Jérôme Crassous, Anniina Salonen, Arnaud Saint-Jalmes, Dominique Langevin

2010-11-25 Paper

DOI: 10.1039/C0CP01152E

Contents

Front/Back Matter

DOI: 10.1039/C0CP90142C

Electronic interactions within composites of polyanilines formed under acidic and alkaline conditions. Conductivity, ESR, Raman, UV-vis and fluorescence studies

L. Dennany, P. C. Innis, S. T. McGovern, G. G. Wallace, Robert J. Forster

2011-01-04 Paper

DOI: 10.1039/C0CP00699H

Front cover

Cover

DOI: 10.1039/C0CP90140G

Elastic deformations in hexagonal phases studied by small-angle X-ray diffraction and simulations

Šárka Perutková, Matej Daniel, Michael Rappolt, Georg Pabst, Gregor Dolinar, Veronika Kralj-Iglič, Aleš Iglič

2010-11-09 Paper

DOI: 10.1039/C0CP01187H

The role of calcium in membrane condensation and spontaneous curvature variations in model lipidic systems

Anan Yaghmur, Barbara Sartori, Michael Rappolt

2010-11-03 Paper

DOI: 10.1039/C0CP01036G

Colloidal metal nanoparticles as a component of designed catalyst

Chun-Jiang Jia, Ferdi Schüth

2011-01-18 Perspective

DOI: 10.1039/C0CP02680H

Back cover

Front/Back Matter

DOI: 10.1039/C1CP90015C

Molecular spin conversion in solid deuterated methane

Piotr Stachowiak

2010-12-20 Paper

DOI: 10.1039/C0CP00943A

Which mechanism operates in the electron-transfer process at liquid/liquid interfaces?

Min Zhou, Shiyu Gan, Lijie Zhong, Xiandui Dong, Li Niu

2010-12-13 Paper

DOI: 10.1039/C0CP01692F

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.