On the liquid mixtures of xenon, alkanes and perfluorinated compounds

Literature Information

Publication Date 2001-06-22
DOI 10.1039/B101519M
Impact Factor 3.676
Authors

Lino M. B. Dias, George Jackson, Eduardo J. M. Filipe


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Abstract

The fluid phase behaviour of binary mixtures of xenon and the lighter perfluoro-n-alkanes, CF4 and C2F6, and of propane and sulfur hexafluoride (SF6) has been examined using the statistical associating fluid theory for potentials of variable attractive range (SAFT-VR). We found that the binary interaction parameters calculated in previous work for (n-alkane + perfluoro-n-alkane) systems and for (Xe + SF6), can be used to predict the existing phase diagrams of (Xe + perfluoro-n-alkane) and (propane + SF6) mixtures, respectively. These results are consistent with the view that mixtures of (xenon + perfluorinated-compound) can be regarded as a special case of mixtures of (n-alkane + perfluorinated-compound) and provide another example of the “alkane-like ” behaviour of xenon previously reported.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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