1,3-Bis(trimethylsilyl)-2lambda~4~-diazathia-1,2-diene
CAS Number:
18156-25-7
Molecular Formula:
C6H18N2SSi2
Characterization of ionophore–metal complexes by infrared multiphoton photodissociation and collision activated dissociation in a quadrupole ion trap mass spectrometer
Literature Information
Publication Date
2000-03-17
DOI
10.1039/A908607B
Impact Factor
4.616
Authors
Jim Shen, Jennifer S. Brodbelt
View Original
Abstract
The formation and fragmentation of a series of metal complexes containing polyether ionophores were studied using electrospray ionization (ESI) methods. Dissociation pathways were analyzed using both collision activated dissociation (CAD) and infrared multiphoton photodissociation (IRMPD) techniques. A number of structurally diagnostic fragment ions were observed, and in many cases the same types of pathways were observed for the alkali, transition, and alkaline earth metal complexes. The dominant fragmentation pathways included dehydration and cleavage across carbon–carbon bonds to produce either type-F or type-A fragments. Energy-resolved CAD and IRMPD experiments, along with double resonance SWIFT, were performed to evaluate the genealogy of fragmentation pathways.
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Source Journal
Analyst
CiteScore:
7.8
Self-citation Rate:
5.6%
Articles per Year:
653
Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
Benzyl 3-(hydroxymethyl)-1-piperazinecarboxylate
CAS Number:
191739-40-9
Molecular Formula:
C13H18N2O3
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