Radiation-induced reactions of benzoyl chloride and acrylates in solution. A pulse radiolysis study

Literature Information

Publication Date 2000-01-22
DOI 10.1039/A907162H
Impact Factor 3.676
Authors

Wolfgang Knolle, Uwe Müller, Reiner Mehnert


View Original

Abstract

Using electron pulse radiolysis with optical detection, the radiation-induced reactions of benzoyl chloride and acrylates were studied in tetrahydrofuran and acetonitrile solution at room temperature. In both solvents electron transfer leads to the formation of transient radical anions of acrylates (k≈2–3×1010 dm3 mol−1 s−1) and of benzoyl chloride (k≈3×1010 dm3 mol−1 s−1). The latter dissociates into chloride ion and the benzoyl radical (k=3×106 s−1), whereas the acrylate anion transforms by protonation into a ketyl-type radical. In mixed solutions a fast electron transfer from acrylate anions to benzoyl chloride is found (k≈1×1010 dm3 mol−1 s−1). The benzoyl chloride anion reacts with the monomer (k=2.8×109 dm3 mol−1 s−1) with simultaneous release of Cl−, forming species which may initiate polymerization. In the presence of oxygen the formation of benzoylperoxy radicals (k=1.6×109 dm3 mol−1 s−1), showing a strong absorption band in the near-UV (λmax=400 nm), is observed.

Related Literature

Thermodynamics and kinetics of carbon deposits on cobalt: a combined density functional theory and kinetic Monte Carlo study

Antonius P. J. Jansen, Ravi Agrawal, Leonardo Spanu

2016-09-19 Paper

DOI: 10.1039/C6CP04719J

Insight into the effects of modifying π-bridges on the performance of dye-sensitized solar cells containing triphenylamine dyes

Shuguang Chen, Hailang Jia, Mengxi Zheng, Kang Shen, Hegen Zheng

2016-10-10 Paper

DOI: 10.1039/C6CP05173A

Unravelling the fundamentals of thermal and chemical expansion of BaCeO3 from first principles phonon calculations

Andreas Løken, Reidar Haugsrud, Tor S. Bjørheim

2016-10-19 Paper

DOI: 10.1039/C6CP05710A

Understanding charge transport in non-doped pristine and surface passivated hematite (Fe2O3) nanorods under front and backside illumination in the context of light induced water splitting

Prince Saurabh Bassi, Li Xianglin, Yanan Fang, Joachim Say Chye Loo, Lydia Helena Wong

2016-10-10 Communication

DOI: 10.1039/C6CP05379C

Composition variation in Al-based dilute nitride alloys using apertureless scanning near-field optical microscopy

G. Kolhatkar, A. Boucherif, C. Dab, S. Fafard, V. Aimez, R. Arès, A. Ruediger

2016-10-13 Paper

DOI: 10.1039/C6CP05063H

Microwave-gated dynamic nuclear polarization

Aurélien Bornet, Arthur Pinon, Lyndon Emsley

2016-09-30 Paper

DOI: 10.1039/C6CP05587G

Orientation order and rotation mobility of nitroxide biradicals determined by quantitative simulation of EPR spectra

Alexey V. Bogdanov, Andrey Kh. Vorobiev

2016-10-20 Paper

DOI: 10.1039/C6CP05815A

Defect chemistry and relaxation processes: effect of an amphoteric substituent in lead-free BCZT ceramics

Indrani Coondoo, Neeraj Panwar, Reddithota Vidyasagar

2016-10-17 Paper

DOI: 10.1039/C6CP06244J

Light-induced charge separation in a P3HT/PC70BM composite as studied by out-of-phase electron spin echo spectroscopy

Mikhail N. Uvarov, Edward J. Reijerse

2016-09-20 Paper

DOI: 10.1039/C6CP05389K

A comparative AFM study of the interfacial nanostructure in imidazolium or pyrrolidinium ionic liquid electrolytes for zinc electrochemical systems

Srđan Begić, Hua Li, Rob Atkin, Anthony F. Hollenkamp, Patrick C. Howlett

2016-09-28 Paper

DOI: 10.1039/C6CP04299F

You might also like

Compound Q&A

How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?

Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...

59713-58-5Ethyl 4-chlorothieno...
Compound Q&A

What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?

5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...

52562-50-25-Methyl-1H-indole-3...
Compound Q&A

What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?

(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...

223418-73-3(1,3-Dimethyl-2,4-di...
Compound Q&A

How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?

Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...

1016983-51-9Sulfocostunolide A
Compound Q&A

What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?

When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...

88478-44-8Murraxocin
Compound Q&A

What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?

Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...

63148-64-1Formvar(R)
Compound Q&A

Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?

(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...

205242-66-6(S)-4-benzyl-2-((ben...
Compound Q&A

What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?

Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...

1447607-69-3Methyl 1-(5-bromo-2-...
Compound Q&A

Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?

2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...

24290-47-92-Methyl-1-phenyl-1-...
Compound Q&A

How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?

3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...

66735-01-13-(4-Bromophenyl)-2-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.