Construction of kinetic phase diagrams

Literature Information

Publication Date
DOI 10.1039/A903245B
Impact Factor 3.676
Authors


View Original

Abstract

It is a noted fact that the composition of a mixed solid phase grown at non-equilibrium can deviate from the equilibrium composition due to the very low diffusion rate in the solid phase. We present an analytical model for the determination of the kinetic composition of a binary solid phase that is growing from a solution at a given supersaturation, giving rise to kinetic phase diagrams. The model is derived for growth at rough surfaces but is expected to apply also to growth at non-roughened surfaces. Kinetic phase diagrams for different undercooling and excess energy parameters are presented and discussed. If the interaction parameters, describing the excess free energy, are large the model equations can have two stable solutions, which implies the simultaneous growth of two solid phases with different compositions. This kinetic phase separation depends on the undercooling and the composition dependence of the attachment probabilities.

Related Literature

Models for biomedical interfaces: a computational study of quinone-functionalized amorphous silica surface features

Marta Corno, Massimo Delle Piane, Patrick Choquet, Piero Ugliengo

2017-02-24 Paper

DOI: 10.1039/C6CP07909A

Can an ammonium-based room temperature ionic liquid counteract the urea-induced denaturation of a small peptide?

Soumadwip Ghosh, Souvik Dey, Mahendra Patel, Rajarshi Chakrabarti

2017-02-22 Paper

DOI: 10.1039/C6CP08842B

Long-range surface plasmon resonance and surface-enhanced Raman scattering on X-shaped gold plasmonic nanohole arrays

Daniel David Galvan, Guowen Meng, Qiuming Yu

2017-08-15 Paper

DOI: 10.1039/C7CP04564F

Modelling of the charge carrier mobility in disordered linear polymer materials

Petr Toman, Miroslav Menšík, Wojciech Bartkowiak, Jiří Pfleger

2017-02-20 Paper

DOI: 10.1039/C6CP07789G

Compositional phase diagram and microscopic mechanism of Ba1−xCaxZryTi1−yO3 relaxor ferroelectrics

Shi-Yu Liu, Yang Meng, Shiyang Liu, De-Jun Li, Yaping Li, Yingdi Liu, Yaogen Shen, Sanwu Wang

2017-07-27 Paper

DOI: 10.1039/C7CP04530A

Understanding CO2 capture mechanisms in aqueous hydrazine via combined NMR and first-principles studies

Byeongno Lee, Haley M. Stowe, Kyu Hyung Lee, Nam Hwi Hur, Son-Jong Hwang, Eunsu Paek, Gyeong S. Hwang

2017-08-18 Paper

DOI: 10.1039/C7CP03803H

Unveiling anomalous CO2-to-N2 selectivity of graphene oxide

Ji Hoon Lee, Hyeon Jeong Lee, Jang Wook Choi

2017-08-08 Paper

DOI: 10.1039/C7CP04318J

Tunable AIEE fluorescence constructed from a triphenylamine luminogen containing quinoline – application in a reversible and tunable pH sensor

Mengmeng Zhang, Wen Yang, Tingfeng Gong, Weiqun Zhou, Renyu Xue

2017-07-18 Paper

DOI: 10.1039/C7CP03234J

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.