Construction of kinetic phase diagrams
Literature Information
It is a noted fact that the composition of a mixed solid phase grown at non-equilibrium can deviate from the equilibrium composition due to the very low diffusion rate in the solid phase. We present an analytical model for the determination of the kinetic composition of a binary solid phase that is growing from a solution at a given supersaturation, giving rise to kinetic phase diagrams. The model is derived for growth at rough surfaces but is expected to apply also to growth at non-roughened surfaces. Kinetic phase diagrams for different undercooling and excess energy parameters are presented and discussed. If the interaction parameters, describing the excess free energy, are large the model equations can have two stable solutions, which implies the simultaneous growth of two solid phases with different compositions. This kinetic phase separation depends on the undercooling and the composition dependence of the attachment probabilities.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




