Homogeneous nucleation and the Ostwald step rule
Literature Information
We compare the pathways for homogeneous nucleation in a number of different systems. In most cases, the simulations show that the nucleation pathways are markedly different from what is assumed in classical nucleation theory. We find that homogeneous nucleation exhibits, at the microscopic level, features that were formulated over a century ago by Ostwald to account for the nucleation of metastable bulk phases. We observe that the structure of the precritical nuclei may differ qualitatively from that of (post)critical nuclei. Surprisingly, in the interface of the larger nuclei, traces of the structure of the smaller nuclei survive.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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