![1-[3-(4-Morpholinylsulfonyl)phenyl]methanamine structure](https://static.chemtradehub.com/structs/933/933989-32-3-51af.webp "1-[3-(4-Morpholinylsulfonyl)phenyl]methanamine structure")
Towards designer polyolefins: highly tuneable olefin copolymerisation using a single permethylindenyl post-metallocene catalyst
Literature Information
Publication Date
2023-12-06
DOI
10.1039/D3SC04861F
Impact Factor
9.825
Authors
Clement G. Collins Rice, Louis J. Morris, Jean-Charles Buffet, Zoë R. Turner, Dermot O'Hare
View Original
Abstract
Using a highly active permethylindenyl-phenoxy (PHENI*) titanium catalyst, high to ultra-high molecular weight ethylene–linear-α-olefin (E/LAO) copolymers are prepared in high yields under mild conditions (2 bar, 30–90 °C). Controllable, efficient, and predictable comonomer enchainment provides access to a continuum of copolymer compositions and a vast range of material properties using a single monomer-agnostic catalyst. Multivariate statistical tools are employed that combine the tuneability of this system with the analytical and predictive power of data-derived models, this enables the targeting of polyolefins with designer properties directly through predictive alteration of reaction conditions.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
1413
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Recommended Compounds
(3-Oxo-1,2,3,4-tetrahydro-2-quinoxalinyl)acetic acid
CAS Number:
136584-14-0
Molecular Formula:
C10H10N2O3
![4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure](https://static.chemtradehub.com/structs/869/869335-75-1-a9d0.webp "4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure")
4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine
CAS Number:
869335-75-1
Molecular Formula:
C8H4ClF3N2
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