N-(4-Chlorobenzyl)-beta-alanine hydrochloride (1:1)
CAS Number:
1172479-10-5
Molecular Formula:
C10H13Cl2NO2
Visible light photoredox-catalyzed deoxydisulfuration of alcohols
Literature Information
Publication Date
2023-11-22
DOI
10.1039/D3QO01742G
Impact Factor
5.281
Authors
Chaoyang Liu, Xiaoman Lin, Delie An
View Original
Abstract
Herein, we present a versatile approach for the photoredox-catalyzed deoxydisulfuration of primary, secondary, and tertiary alcohols, utilizing tetrasulfides to facilitate the efficient synthesis of unsymmetrical disulfides. The reaction mechanism involves the in situ generation of alkyloxy-2-oxoacetic acid, followed by subsequent decarboxylative alkyl radical substitution onto the tetrasulfide reagent. This method boasts several noteworthy features, including mild reaction conditions, a wide range of applicable substrates, easily obtainable starting materials, and the capability of scaling up to gram quantities. These features collectively underscore the generality and practicality of this novel disulfuration approach.
Related Literature
Theoretical study of electronically excited radical cations of naphthalene and anthracene as archetypal models for astrophysical observations. Part I. Static aspects‡
S. Ghanta, V. Sivaranjana Reddy, S. Mahapatra
2011-07-12
Paper
DOI: 10.1039/C1CP21083A
Electrocatalytic oxygen evolution from water on a Mn(iii–v) dimer model catalyst—A DFT perspective
I. Panas
2011-07-20
Paper
DOI: 10.1039/C0CP02132F
Voltammetry and in situscanning tunnelling spectroscopy of osmium, iron, and ruthenium complexes of 2,2′:6′,2′′-terpyridine covalently linked to Au(111)-electrodes
Princia Salvatore, Allan Glargaard Hansen, Thomas Bjørnholm, Richard John Nichols, Jens Ulstrup
2011-06-23
Paper
DOI: 10.1039/C1CP21197H
Nanoparticle-coated separators for lithium-ion batteries with advanced electrochemical performance
Jason Fang, Antonios Kelarakis, Yueh-Wei Lin, Chi-Yun Kang, Ming-Huan Yang, Cheng-Liang Cheng, Yue Wang, Emmanuel P. Giannelis, Li-Duan Tsai
2011-07-06
Communication
DOI: 10.1039/C1CP22017A
Electron-beam evaporated silicon as a top contact for molecular electronic device fabrication
Rajesh Kumar, Haijun Yan, Adam Johan Bergren
2011-06-23
Paper
DOI: 10.1039/C1CP20755E
The origin of dips for the graphene-based DNA sequencing device
Yeonchoo Cho, Seung Kyu Min, Woo Youn Kim, Kwang S. Kim
2011-05-26
Communication
DOI: 10.1039/C1CP20760A
Quantum design rules for single molecule logic gates
N. Renaud, M. Hliwa, C. Joachim
2011-07-27
Paper
DOI: 10.1039/C1CP21221D
[MLn]2+ doubly charged systems: modeling, bonding, life times and unimolecular reactivity
2011-07-18
Perspective
DOI: 10.1039/C1CP20622B
You might also like
Compound Q&A
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
615-45-22-Methylbenzene-1,4-...
Compound Q&A
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
871826-15-2(6-Chloropyridazin-3...
Compound Q&A
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
77772-72-62-Fluoro-3-methylphe...
Compound Q&A
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
177476-75-43-Methoxy-4-nitroben...
Compound Q&A
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
90347-86-74-Ethynylbenzamide
Compound Q&A
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
102196-18-92-[4-(Hydroxymethyl)...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(S)-(9H-Fluoren-9-yl)methyl (pyrrolidin-2-ylmethyl)carbamate hydrochloride
CAS Number:
1217813-15-4
Molecular Formula:
C20H23ClN2O2
1-(3-Fluorophenyl)-1H-1,2,4-triazole-3-carboxylic acid
CAS Number:
1292369-51-7
Molecular Formula:
C9H6FN3O2
![[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure](https://static.chemtradehub.com/structs/509/50918-26-8-4ce8.webp "[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure")
[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid
CAS Number:
50918-26-8
Molecular Formula:
C5H6N2O2S2
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.