Impact of exposed crystal facets on oxygen reduction reaction activity in zeolitic imidazole frameworks
Literature Information
Publication Date
2023-08-08
DOI
10.1039/D3DT02172F
Impact Factor
4.39
Authors
Sorawich Pimu, Nuttapon Yodsin, Sirawee Maneewan, Jaruwan Kanthachan, Supawadee Namuangruk, Kanokwan Kongpatpanich
View Original
Abstract
ZIF-67 is a representative type of metal–organic framework (MOF) developed for the oxygen reduction reaction (ORR) owing to its robust structure in alkaline electrolytes and the presence of the redox-active Co2+ species in the structure. In this work, the improvement of the ORR electrolytic performance of ZIF-67 in its pure phase by optimization of its crystal morphology and crystal facets has been presented. ZIF-67 nanocubes exhibit higher ORR activity than their bulk crystals. The enriched (100) facet in the nanocube crystals provides a higher number of exposed Co2+ sites resulting in improved ORR performances. Moreover, DFT study suggests a distinguished mechanism in the (100) facet highlighting the importance of crystal facets in electrochemical performances.
Recommended Journals
Related Literature
Buffers more than buffering agent: introducing a new class of stabilizers for the protein BSA
Bhupender S. Gupta, Mohamed Taha, Ming-Jer Lee
2014-11-06
Paper
DOI: 10.1039/C4CP04663C
Re-visiting the O/Cu(111) system – when metastable surface oxides could become an issue!
Norina A. Richter, Chang-Eun Kim, Catherine Stampfl, Aloysius Soon
2014-10-28
Paper
DOI: 10.1039/C4CP04473H
Tailoring the interface of an immiscible polymer blend by a mutually miscible homopolymer grafted onto graphene oxide: outstanding mechanical properties
Goutam Prasanna Kar, Sourav Biswas, Suryasarathi Bose
2014-11-21
Paper
DOI: 10.1039/C4CP04481A
The importance of inversion disorder in the visible light induced persistent luminescence in Cr3+ doped AB2O4 (A = Zn or Mg and B = Ga or Al)
Neelima Basavaraju, Kaustubh R. Priolkar, Didier Gourier, Suchinder K. Sharma, Aurélie Bessière, Bruno Viana
2014-11-24
Paper
DOI: 10.1039/C4CP03866E
Molecular charge transfer by adsorbing TCNQ/TTF molecules via π–π interaction: a simple and effective strategy to modulate the electronic and magnetic behaviors of zigzag SiC nanoribbons
Dan Liu, Guangtao Yu, Yuanhui Sun, Xuri Huang, Jia Guan, Hui Zhang, Hui Li, Wei Chen
2014-11-05
Paper
DOI: 10.1039/C4CP03690E
Alkane separation using nanoporous graphene membranes
Krzysztof Nieszporek, Mateusz Drach
2014-11-11
Paper
DOI: 10.1039/C4CP02745K
Autocatalytic growth of ZnO nanorods from flat Au(111)-supported ZnO films
Leandro Pascua, Hans-Joachim Freund
2014-10-27
Paper
DOI: 10.1039/C4CP03730H
A facile one-pot method to synthesize a three-dimensional graphene@carbon nanotube composite as a high-efficiency microwave absorber
2014-11-17
Paper
DOI: 10.1039/C4CP04745A
Using beryllium bonds to change halogen bonds from traditional to chlorine-shared to ion-pair bonds
Ibon Alkorta, José Elguero, Otilia Mó, Manuel Yáñez, Janet E. Del Bene
2014-11-28
Paper
DOI: 10.1039/C4CP04574B
You might also like
Compound Q&A
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
858-46-82,4,6-Tris(pentafluo...
Compound Q&A
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
56787-36-1Chloroac-nle-oh
Compound Q&A
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
55095-15-3alpha-(2-Bromophenyl...
Compound Q&A
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
139585-48-12-Chloro-5-methoxypy...
Compound Q&A
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
12036-22-5Tungsten(IV) oxide
Source Journal
Dalton Transactions
CiteScore:
6.6
Self-citation Rate:
11.4%
Articles per Year:
1868
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant. Specific guidance for some areas of our scope is given below.
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.