Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes

Literature Information

Publication Date 2023-12-19
DOI 10.1039/D3CC05709G
Impact Factor 6.222
Authors

Fabian Müller, Clara Schweinzer, Fernando Casas, Bruno Pribanic, Grégoire Le Corre, Debora Thöny, Monica Trincado, Hansjörg Grützmacher


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Abstract

Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru–Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (BxNxHy), predominantly B21N21H18, the BN analogue of superbenzene.

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