Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes
Literature Information
Fabian Müller, Clara Schweinzer, Fernando Casas, Bruno Pribanic, Grégoire Le Corre, Debora Thöny, Monica Trincado, Hansjörg Grützmacher
Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru–Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (BxNxHy), predominantly B21N21H18, the BN analogue of superbenzene.
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