Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers

Literature Information

Publication Date 2024-01-02
DOI 10.1039/D3CC05689A
Impact Factor 6.222
Authors

Asuka Nishibe, Ryohei Akiyoshi, Akinori Saeki, Kazuyoshi Ogasawara, Takaaki Tsuruoka, Daisuke Tanaka


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Abstract

One-dimensional (1D) Cd(II) coordination polymers [Cd(x-SPhOMe)2]n (x = ortho, meta, and para; HSPhOMe = methoxybenzenethiol) containing inorganic 1D (–Cd–S–)n chains were synthesized. Among these, the KGF-31 polymer bearing para-SPhOMe featured a three-strand chain structure assembled via interchain S⋯S interactions and exhibited high photoconductivity and longevity.

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