Iridium-catalyzed selective arylation of B(6)–H of 3-aryl-o-carboranes with arylboronic acid via direct B–H activation

Literature Information

Publication Date 2024-01-02
DOI 10.1039/D3CC05630A
Impact Factor 6.222
Authors

Han-Bo Yang, Yan Guo, Ke Cao, Qi-Jia Jiang, Chao-Chao Teng, Dao-Yong Zhu, Shao-Hua Wang


View Original

Abstract

This work discloses an iridium-catalyzed selective arylation of B(6)–H of 3-Ar-o-carboranes with arylboronic acid via direct B–H activation for the first time. A series of unsymmetric and symmetric 3,6-diaryl-o-carboranes decorated with diverse active groups have been synthesized with moderate to excellent yields under mild conditions. This work offers an efficient approach for selective arylation of B(6)–H with arylboronic acid and has important value for selective functionalization of o-carboranes.

Related Literature

A photo-responsive organogel

Julian Eastoe, Margarita Sánchez-Dominguez, Paul Wyatt, Richard K. Heenan

2004-10-01 Communication

DOI: 10.1039/B410158H

11-Aminoundecanoic acid: a versatile unit for the generation of low molecular weight gelators for water and organic solvents

Anthony D'Aléo, Jean-Luc Pozzo, Frédéric Fages, Marc Schmutz, Gudrun Mieden-Gundert, Fritz Vögtle, Vesna Caplar, Mladen Zinic

2003-11-18 Communication

DOI: 10.1039/B307846A

Intramolecular charge separation in a hydrogen bonded tyrosine–ruthenium(ii)–naphthalene diimide triad

Olof Johansson, Henriette Wolpher, Magnus Borgström, Leif Hammarström, Jonas Bergquist, Licheng Sun, Björn Åkermark

2003-11-19 Communication

DOI: 10.1039/B308101J

[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh2(OH)

Victorio Cadierno, Josefina Díez, Sergio E. García-Garrido, José Gimeno

2004-10-14 Communication

DOI: 10.1039/B410812D

Unprecedented Barbier-type reactions catalysed by titanocene(iii)

Antonio Rosales, Juan L. Oller-López, José Justicia, Andreas Gansäuer, J. Enrique Oltra, Juan M. Cuerva

2004-10-05 Communication

DOI: 10.1039/B411173G

Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10]

Jonathan Bould, Yvonne M. McInnes, Michael J. Carr, John D. Kennedy

2004-09-23 Communication

DOI: 10.1039/B406974A

Synthesis and photocleavage of a new dimeric bis(o-nitrobenzyl) diether tether

Nandita Madhavan, Mary S. Gin

2004-10-14 Communication

DOI: 10.1039/B408482A

A simulation of key aspects of a primary process in natural photosynthesis by a Langmuir–Blodgett film assembly

Masaru Sakomura, Kazuyoshi Ueda, Masamichi Fujihira

2004-09-29 Communication

DOI: 10.1039/B410262B

You might also like

Compound Q&A

What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?

When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...

71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A

What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?

4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...

224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A

How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?

Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...

2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A

What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?

(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...

909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?

2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...

1254120-14-32-Methyl-2-propanyl ...
Compound Q&A

Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?

There are alternative reagents that can be used in synthesis instead of (E)-4-(t...

135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A

What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?

[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...

121202-20-8[2-(3-Chlorophenyl)-...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A

What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?

The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...

42865-19-01-Bromo-2-isocyanato...
Compound Q&A

What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?

4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...

147065-06-34-Nitro-D-phenylalan...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.