Time-resolved radioluminescence of the Cu(i) cluster Cu4I62−. Different responses to photo, X-ray, β-ray and α-particle excitation

Literature Information

Publication Date 2023-11-03
DOI 10.1039/D3CC04870E
Impact Factor 6.222
Authors

John V. Garcia, Camilo Guzman, Alexander A. Mikhailovsky, Sean Devitt, James R. Tinsley, John A. DiBenedetto, Peter C. Ford


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Abstract

Time-resolved radioluminescence (TRRL) properties of the Cu(I) cluster Cu4I62− upon pulsed X-ray, β-ray or α-particle excitation are described. The longer (>2 μs) TRRL component displays exponential decay comparable to pulsed UV excitation; however, temporal behaviour at shorter times indicates that high local excited state density provides an alternative decay channel.

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