Accessing Ni(0) to Ni(IV) via nickel–carbon–phosphorus bond reorganization

Literature Information

Publication Date 2023-11-23
DOI 10.1039/D3CC04687G
Impact Factor 6.222
Authors

Lirong Lin, David S. Tresp, Denis M. Spasyuk, Roger A. Lalancette, Demyan E. Prokopchuk


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Abstract

Two-electron oxidation of a NiIIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η6-arylphosphonium moiety coordinated to NiII. The reaction is fully reversible under reducing conditions. X-ray crystallography, NMR/EPR spectroscopy, electrochemistry, and DFT calculations support the proposed Ni–C–P bond reorganization mechanisms, which access oxidation states from Ni0 to NiIV.

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