Accessing Ni(0) to Ni(IV) via nickel–carbon–phosphorus bond reorganization
Literature Information
Lirong Lin, David S. Tresp, Denis M. Spasyuk, Roger A. Lalancette, Demyan E. Prokopchuk
Two-electron oxidation of a NiIIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η6-arylphosphonium moiety coordinated to NiII. The reaction is fully reversible under reducing conditions. X-ray crystallography, NMR/EPR spectroscopy, electrochemistry, and DFT calculations support the proposed Ni–C–P bond reorganization mechanisms, which access oxidation states from Ni0 to NiIV.
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