D–A–D–T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes
Literature Information
Ren-Xiang Liu, Xin Chen, Luo Yang
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction involving an aldehyde, two different alkenes and TMSN3 is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes via a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
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