Inverse vulcanization of trimethoxyvinylsilane particles
Literature Information
Alexander P. Grimm, Johannes M. Scheiger, Peter W. Roesky
Elemental sulfur, a highly abundant waste product from natural gas and oil refining, can be used to create polymeric materials when reacted with unsaturated organic comonomers at elevated temperatures. Herein, we report on the inverse vulcanization of trimethoxyvinylsilane (TMVS) particles to obtain sulfur coated TMVS-sulfur (TMVS-S) particles with a sulfur content of 18.85 wt%. TMVS-S particles exhibit a high surface-to-volume ratio, insolubility, and can further be functionalized with N-vinylimidazole (NVIA) to incorporate N-donor ligands, known for copper(II) complexation. Adsorption experiments with aqueous solutions of mercury(II) and copper(II) ions revealed very good distribution coefficients of TMVS-S-NVIA particles for mercury and copper remediation, showcasing possibilities arising from combining inorganic siloxane and sulfur polymers towards novel adsorbent materials derived from abundant and commercially available compounds.
Related Literature
Phase evolution of magnetron sputtered nanostructured ATO on grid during lithiation–delithiation processes as model electrodes for Li-ion battery
Pan Ouyang, Hong Zhang, Yulong Liu, Ying Wang
DOI: 10.1039/C3CP54252A
Unravelling the impact of obstacles in diffusion and kinetics of an enzyme catalysed reaction
Márcio Mourão, Doree Kreitman
DOI: 10.1039/C3CP52417E
Si photoanode protected by a metal modified ITO layer with ultrathin NiOx for solar water oxidation
Ke Sun, Shaohua Shen, Justin S. Cheung, Xiaolu Pang, Namseok Park, Jigang Zhou, Yongfeng Hu, Zhelin Sun, Sun Young Noh, Conor T. Riley, Paul K. L. Yu, Sungho Jin
DOI: 10.1039/C4CP00033A
Three-dimensional superdiffusive chemical waves in a precipitation system
M. M. Ayass, I. Lagzi, M. Al-Ghoul
DOI: 10.1039/C4CP02587C
Microscopic interactions of the imidazolium-based ionic liquid with molecular liquids depending on their electron-donicity
Toshiyuki Takamuku, Hiroshi Hoke, Abdenacer Idrissi, Myriam Moreau, Yusuke Honda, Tatsuya Umecky, Takuya Shimomura
DOI: 10.1039/C4CP03565H
Electronic structure–sunlight driven water splitting activity correlation of (Zn1−yGay)(O1−zNz)
Sivaraman RajaAmbal, A. K. Yadav, S. N. Jha, D. Bhattacharyya
DOI: 10.1039/C4CP03640A
Viologen-based ionic liquid crystals: induction of a smectic A phase by dimerisation
Girolamo Casella, Valerio Causin, Federico Rastrelli, Giacomo Saielli
DOI: 10.1039/C3CP54628D
Destructuring ionic liquids in ionogels: enhanced fragility for solid devices
A. Guyomard-Lack, P.-E. Delannoy, N. Dupré, C. V. Cerclier, B. Humbert, J. Le Bideau
DOI: 10.1039/C4CP03187C
You might also like
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
Source Journal
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.











![8-Bromo-6-fluoro[1,2,4]triazolo[1,5-a]pyridin-2-amine structure 8-Bromo-6-fluoro[1,2,4]triazolo[1,5-a]pyridin-2-amine structure](https://static.chemtradehub.com/structs/125/1257705-51-3-9f4a.webp)
![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure (R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp)

