Destructuring ionic liquids in ionogels: enhanced fragility for solid devices
Literature Information
A. Guyomard-Lack, P.-E. Delannoy, N. Dupré, C. V. Cerclier, B. Humbert, J. Le Bideau
Confining ionic liquids (ILs) with added lithium salt within silica host networks enhances their fragility and improves their conductivity. Overall, conductivity measurements, Raman spectroscopy of the TFSI anion and NMR spectroscopy of the lithium cation show segregative interaction of lithium ions with the SiO2 host matrix. This implies at IL/SiO2 interfaces a breakdown of aggregated regions that are found systematically in bulk ILs. Such destructuration due to the interface effect determines the fragility and thus results locally at the interface in short relaxation times, low viscosity, and good ionic conductivity. The “destructuration” of ion pairs or domains makes ILs within ionogels a competitive alternative to existing solid ionic conductors in all-solid devices, such as lithium batteries and supercapacitors.
Related Literature
A multi-responsive turn-on flurogenic probe to sense Zn2+, Cd2+ and Pb2+: left-right-center emission signal swing
Soham Samanta, Barun Kumar Datta, Madhurima Boral, Abhijit Nandan, Gopal Das
DOI: 10.1039/C6AN00657D
Fabrication of magnetic trimetallic metal–organic frameworks for the rapid removal of tetracycline from water
Rui Xiao, Hassan Idris Abdu, Liping Wei, Tieying Wang, Shuhui Huo, Jing Chen
DOI: 10.1039/C9AN02481F
Live-cell quantification and comparison of mammalian oocyte cytosolic lipid content between species, during development, and in relation to body composition using nonlinear vibrational microscopy
Joshua Jasensky, Andrew P. Boughton, Alexander Khmaladze, Jun Ding, Chi Zhang, Jason E. Swain, George W. Smith
DOI: 10.1039/C6AN00629A
Development of a rechargeable optical hydrogen peroxide sensor – sensor design and biological application
Klaus Koren, Peter Ø. Jensen
DOI: 10.1039/C6AN00864J
An FcεRI-IgE-based genetically encoded microfluidic cell sensor for fast Gram-negative bacterial screening in food samples
Jun Yang, Donglei Jiang, Xiulan Sun
DOI: 10.1039/C9AN02289A
Acetylcholinesterase-catalyzed silver deposition for ultrasensitive electrochemical biosensing of organophosphorus pesticides
Zhenhui Liu, Xin Xia, Guoxing Zhou, Lei Ge, Feng Li
DOI: 10.1039/C9AN02546D
Measurement of serum phosphate levels using a mobile sensor
Sarah Esparza, Dimei Wu, Mark R. Hanudel, Barbara Gales, Isidro B. Salusky
DOI: 10.1039/C9AN02215E
Mathematical chromatography deciphers the molecular fingerprints of dissolved organic matter
Urban J. Wünsch, Jeffrey A. Hawkes
DOI: 10.1039/C9AN02176K
A label-free fluorescent adenosine triphosphate biosensor via overhanging aptamer-triggered enzyme protection and target recycling amplification
Zhaoyin Wang, Jian Zhao, Zhihui Dai
DOI: 10.1039/C6AN00816J
A FT-NIR spectroscopy methodology to estimate firing distance based on the direct analysis of the bullet impact surface
Jorge M. G. Sarraguça, Catarina Lima, Filipe Machado, João A. Lopes, Agostinho Almeida, Luís Fernandes
DOI: 10.1039/C6AN00247A
You might also like
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1) structure [(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/141/1416444-88-6-e06a.webp)

![5,10-Dihydroindeno[2,1-a]indene structure 5,10-Dihydroindeno[2,1-a]indene structure](https://static.chemtradehub.com/structs/654/6543-29-9-71ca.webp)
![6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure](https://static.chemtradehub.com/structs/564/564-94-3-e746.webp)