Length dependence thermal conductivity of zinc selenide (ZnSe) and zinc telluride (ZnTe) – a combined first principles and frequency domain thermoreflectance (FDTR) study
Literature Information
Rajmohan Muthaiah, Roshan Sameer Annam, Fatema Tarannum, Ashish Kumar Gupta, Jivtesh Garg, Shamsul Arafin
In this study, we report the length dependence of thermal conductivity (k) of zinc blende-structured Zinc Selenide (ZnSe) and Zinc Telluride (ZnTe) for length scales between 10 nm and 10 μm using first-principles computations, based on density-functional theory. The k value of ZnSe is computed to decrease significantly from 22.9 W m−1 K−1 to 1.8 W m−1 K−1 as the length scale is diminished from 10 μm to 10 nm. The k value of ZnTe is also observed to decrease from 12.6 W m−1 K−1 to 1.2 W m−1 K−1 for the same decrease in length. We also measured the k of bulk ZnSe and ZnTe using the Frequency Domain Thermoreflectance (FDTR) technique and observed a good agreement between the FDTR measurements and first principles calculations for bulk ZnSe and ZnTe. Understanding the thermal conductivity reduction at the nanometer length scale provides an avenue to incorporate nanostructured ZnSe and ZnTe for thermoelectric applications.
Related Literature
Influence of additives on the structure of surfactant-free microemulsions
J. Marcus, D. Touraud, S. Prévost, O. Diat, T. Zemb, W. Kunz
DOI: 10.1039/C5CP06364G
Quantitative monitoring of the removal of non-encapsulated material external to filled carbon nanotube samples
Markus Martincic, Elzbieta Pach, Belén Ballesteros, Gerard Tobias
DOI: 10.1039/C5CP04664E
In situ 2D-extraction of DNA wheels by 3D through-solution transport
Keitel Cervantes-Salguero, Waka Nakanishi, Ibuki Kawamata, Kosuke Minami, Hirokazu Komatsu, Satoshi Murata
DOI: 10.1039/C5CP05765E
CO2 adsorption–desorption performance of mesoporous zirconium hydroxide with robust water durability
Y. Kamimura, A. Endo
DOI: 10.1039/C5CP05211D
An auxilliary grid method for the calculation of electrostatic terms in density functional theory on a real-space grid
Michael Zuzovski, Amir Boag, Amir Natan
DOI: 10.1039/C5CP01090J
Theoretical study on the dehydrogenation reaction of dihydrogen bonded phenol–borane-trimethylamine in the excited state
Yonggang Yang, Yufang Liu, Dapeng Yang, Hui Li, Kai Jiang, Jinfeng Sun
DOI: 10.1039/C5CP02530C
Enhanced thermal energy harvesting performance of a cobalt redox couple in ionic liquid–solvent mixtures
Manoj A. Lazar, Danah Al-Masri, Douglas R. MacFarlane, Jennifer M. Pringle
DOI: 10.1039/C5CP04305K
Synthesis of hollow cobalt oxide nanopowders by a salt-assisted spray pyrolysis process applying nanoscale Kirkendall diffusion and their electrochemical properties
Hyeon Seok Ju, Jung Sang Cho, Jong Hwa Kim, Yun Ju Choi, Yun Chan Kang
DOI: 10.1039/C5CP06206C
Stability of two-dimensional PN monolayer sheets and their electronic properties
ShuangYing Ma, Chaoyu He, L. Z. Sun, Haiping Lin, Youyong Li, K. W. Zhang
DOI: 10.1039/C5CP05901A
You might also like
What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?
When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...
What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?
5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...
How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?
(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...
What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?
Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...
What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?
1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...
Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?
Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...
What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?
The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...
What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?
2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...
How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?
2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...
Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?
N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![2-Bromo-7-chloro-4H-pyrrolo[2,3-b]pyrazine structure 2-Bromo-7-chloro-4H-pyrrolo[2,3-b]pyrazine structure](https://static.chemtradehub.com/structs/115/1150617-58-5-0b0a.webp)
![4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide structure 4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide structure](https://static.chemtradehub.com/structs/558/5581-42-0-7dcb.webp)

