Second ionization constant of sulfuric acid in H2O and D2O from 150 to 300 °C at p = 11.5 MPa using flow AC conductivity

Literature Information

Publication Date 2022-12-21
DOI 10.1039/D2CP01761J
Impact Factor 3.676
Authors

Jacy K. Conrad, Hugues Arcis, Jane P. Ferguson, Peter R. Tremaine


View Original

Abstract

A custom-built flow-through AC conductivity instrument was used to measure the deuterium isotope effect on the ionization quotient of bisulfate from 150 to 300 °C, at p = 11.5 MPa. Standardized solutions of KCl, HCl, KOH, KHSO4, K2SO4, and H2SO4 were prepared in light and heavy waters and their conductivities were measured and fitted with the Quint–Viallard conductivity model to obtain single ion conductivities at infinite dilution for K+, Cl−, H+, OH−, HSO4−, and SO42−. These are the first conductivities of DSO4− and SO42− measured in heavy water at any temperature, and the first ionization constants for bisulfate reported in heavy water above 225 °C. The deuterium isotope effect on the chemical equilibrium constant, ΔpK2a = pK2a,D − pK2a,H, was found to increase with temperature, in contrast to the behaviour seen for other simple oxyacids.

Related Literature

Molecular weight prediction with no dependence on solvent viscosity. A quantitative pulse field gradient diffusion NMR approach

Francisco M. Arrabal-Campos, Pascual Oña-Burgos

2016-06-06 Communication

DOI: 10.1039/C6PY00691D

Direct arylation polymerization of asymmetric push–pull aryl halides

Liyan You, Saadia T. Chaudhry, Yan Zhao, Junchen Liu, Xikang Zhao, Jiazhi He, Jianguo Mei

2017-04-06 Communication

DOI: 10.1039/C7PY00237H

Inside front cover

Cover

DOI: 10.1039/C7PY90095C

Formation of long sub-chain hyperbranched poly(methyl methacrylate) based on inhibited self-cyclization of seesaw macromonomers

Peng-Yun Li, Wei-Dong He, Sheng-Qi Chen, Xiao-Xia Lu, Jia-Min Li, Hui-Juan Li

2016-06-27 Paper

DOI: 10.1039/C6PY00583G

Body temperature-responsive two-way and moisture-responsive one-way shape memory behaviors of poly(ethylene glycol)-based networks

Xueyang Liu, Alfred Iing Yoong Tok, Vitali Lipik

2017-06-07 Paper

DOI: 10.1039/C7PY00786H

Synthesis and application of a novel poly-l-phenylalanine electroactive macromonomer as matrix for the biosensing of ‘Abused Drug’ model

Z. Pinar Gumus, Huseyin Akbulut, Ebru Aldemir, Hakan Coskunol, Demet Goen Colak, Shuhei Yamada, Takeshi Endo, Yusuf Yagci

2016-11-02 Paper

DOI: 10.1039/C6PY01764A

Facile synthesis and the properties of novel cardo poly(arylene ether sulfone)s with pendent cycloaminium side chains as anion exchange membranes

Ruiqiang Wang, Xinbing Chen, Pei Chen, Zhongwei An, Suobo Zhang

2017-06-20 Paper

DOI: 10.1039/C7PY00690J

Amphipathic metal-containing macromolecules with photothermal properties

Xumin He, Xiehua He, Shenyan Li, Kaiyue Zhuo, Weixiang Qin, Shuyu Dong, Jiangxi Chen, Lei Ren, Gang Liu, Haiping Xia

2017-05-15 Communication

DOI: 10.1039/C7PY00641A

You might also like

Compound Q&A

What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?

When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...

1498311-57-12-Methyl-2-propanyl ...
Compound Q&A

What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?

5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...

1000572-93-95-Bromo-1,2-dichloro...
Compound Q&A

How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?

(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...

354153-64-3(2R)-2-Amino-2-(4-br...
Compound Q&A

What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?

Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...

362707-24-2Methyl 4-(aminomethy...
Compound Q&A

What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?

1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...

1174834-52-61,4-dimethyl-1H-pyra...
Compound Q&A

Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?

Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...

239-69-0Dinaphtho[1,2-b:2',1...
Compound Q&A

What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?

The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...

612-37-37-Methyl-7,9-dihydro...
Compound Q&A

What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?

2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...

205676-17-12-(4-Chlorophenyl)ma...
Compound Q&A

How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?

2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...

3351-32-42-Methylchrysene
Compound Q&A

Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?

N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...

89533-23-3N-(6-aminopyrimidin-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.