Recent advances in dendrite-free lithium metal anodes for high-performance batteries

Literature Information

Publication Date 2022-08-05
DOI 10.1039/D2CP01655A
Impact Factor 3.676
Authors

Xiang Zhang, Chunwen Sun


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Abstract

With the merits of high energy density, light weight, and low electrode potential, lithium metal anodes (LMAs) have lately sparked worldwide attention in the field of batteries. However, their low Coulombic efficiency, tremendous volume expansion, and serious dendrite growth make lithium metal batteries (LMBs) unsuitable for a wide variety of applications. Moreover, when lithium dendrite crosses the electrolyte and reaches the cathode material, it may cause short circuit and safety issues for batteries. Herein, to accelerate the development of LMBs, we give a brief summary of the dendrite growth mechanisms in both liquid and solid systems of electrolytes. In particular, various modification approaches to dendrite-free lithium metal batteries are discussed. Furthermore, advanced in situ characterization techniques for the real-time observation of lithium dendrite growth are presented. To address the application issues, various potential research routes for improving the performance of LMBs are provided as well.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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