3D printed nickel catalytic static mixers made by corrosive chemical treatment for use in continuous flow hydrogenation

Literature Information

Publication Date 2021-11-15
DOI 10.1039/D1RE00456E
Impact Factor 4.239
Authors

Milan Kundra, Yutong Zhu, Xuan Nguyen, Darren Fraser, Christian H. Hornung, John Tsanaktsidis


View Original

Abstract

Catalytic static mixers, 3D printed from nickel alloys, were treated with etching or leaching solutions to activate their surfaces for use in hydrogenation of alkenes, aldehydes and nitro-groups. Their performance was benchmarked against industrial standard alumina catalysts, using a tubular continuous flow reactor. These novel structured catalysts were additively manufactured from printer-grade Monel and Inconel powders. Especially the Monel-type catalysts, consisting predominantly of nickel and copper by weight, presented a surface layer significantly enriched in nickel after the leaching protocol, which resulted in a high catalytic activity and a surprising selectivity towards unsubstituted double bonds.

Related Literature

Preparation and structure of Fe-containing aluminosilicate thin films

Héloïse Tissot, Linfei Li, Shamil Shaikhutdinov, Hans-Joachim Freund

2016-08-11 Paper

DOI: 10.1039/C6CP03460H

pH-Responsive drug release and NIR-triggered singlet oxygen generation based on a multifunctional core–shell–shell structure

Renlu Han, Haopeng Yi, Junhui Shi, Zongjun Liu, Hao Wang, Yafei Hou, You Wang

2016-08-19 Paper

DOI: 10.1039/C6CP05308D

Structure-dependent vibrational dynamics of Mg(BH4)2 polymorphs probed with neutron vibrational spectroscopy and first-principles calculations

James L. White, Wei Zhou, Vitalie Stavila, Leonard E. Klebanoff, Terrence J. Udovic

2016-08-19 Paper

DOI: 10.1039/C6CP04469G

A new insight into π–π stacking involving remarkable orbital interactions

Rundong Zhao, Rui-Qin Zhang

2016-08-18 Paper

DOI: 10.1039/C6CP05485D

An alternative explanation of the cononsolvency of poly(N-isopropylacrylamide) in water–methanol solutions

Andrea Pica, Giuseppe Graziano

2016-08-26 Paper

DOI: 10.1039/C6CP04753J

C96H30 tailored single-layer and single-crystalline graphene quantum dots

Xingming Sun, Jun Yan, Zheng Xie, Ping Chen, Shuyun Zhou

2016-08-11 Paper

DOI: 10.1039/C6CP03453E

Calculation of Raman parameters of real-size zigzag (n, 0) single-walled carbon nanotubes using finite-size models

Teobald Kupka, Michal Stachów, Leszek Stobiński, Jakub Kaminský

2016-08-11 Paper

DOI: 10.1039/C6CP04100K

Influence of counterions on the conformation of conjugated polyelectrolytes: the case of poly(thiophen-3-ylacetic acid)

Gregor Hostnik, Matjaž Bončina, Caterina Dolce, Guillaume Mériguet, Anne-Laure Rollet, Janez Cerar

2016-08-11 Paper

DOI: 10.1039/C6CP04193K

You might also like

Compound Q&A

What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?

When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...

16712-20-2Lithium chloride hyd...
Compound Q&A

Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?

4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...

690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A

How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?

Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...

16733-85-01,3-Thiazole-2-carbo...
Compound Q&A

What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?

5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...

934175-58-35-(Difluoromethyl)-2...
Compound Q&A

How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?

Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...

22288-79-5Methyl 3-acetamido-2...
Compound Q&A

What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?

4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...

34846-65-64-Isoquinolinecarbon...
Compound Q&A

How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?

Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...

877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A

What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?

6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...

1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A

Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?

(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...

23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A

What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?

7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....

1293987-84-47-bromo-3-methyl-3,4...

Source Journal

Reaction Chemistry & Engineering

Reaction Chemistry & Engineering
CiteScore: 0
Self-citation Rate: 8.8%
Articles per Year: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.