Synthetic platform for mono-functionalised tridentate macrocycles as key precursors of mechanically-linked macromolecular systems
Literature Information
Publication Date
2021-03-08
DOI
10.1039/D1QO00245G
Impact Factor
5.281
Authors
Atul Kumar Sharma, Jagadeesh Malineni, Simon Box, Sina Ghiassinejad, Evelyne van Ruymbeke, Charles-André Fustin
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Abstract
We report here a synthetic platform toward mono-functionalized tridentate macrocycles based on a pyridine-2,6-bis-carboxamide motif. These macrocycles bear a variety of functional groups at the fourth position of the pyridine, giving access to a wide range of synthetic methods for further derivatisation or preparation of more complex structures such as mechanically interlocked molecules or polymer materials. To illustrate the potential of this family of macrocycles a series of square planar palladium complex-based pseudorotaxanes, containing different axles and functional groups on the ring, are synthesised, and then used to prepare a macro-pseudorotaxane, i.e. a polymer containing a rotaxane junction, and mechanically-linked gels by a one-pot and a polyrotaxane approach.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
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5-Bromo-2-chloro-N-methoxy-N-methylisonicotinamide
CAS Number:
1256790-08-5
Molecular Formula:
C8H8BrClN2O2
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