Photo-induced weak base-catalyzed synthesis of α-haloboronates from vinylboronates and polyfluoroalkyl halides
Literature Information
Publication Date
2021-02-26
DOI
10.1039/D1QO00169H
Impact Factor
5.281
Authors
Tongchang Fang, Jian Qiu, Kai Yang
View Original
Abstract
Organoboron compounds play an important role in various fields due to the diverse transformations of C–B bonds. The introduction of easy-to-transform functional groups into organoboron compounds would greatly increase their synthetic application value. This article reports the first synthesis of sp2-α-haloboronates via an in situ α-sp3-boron radical intermediate, and proved their high synthetic application value through subsequent transformations.
Related Literature
Self-assembly of a novel pentanuclear centred-tetrahedral silver species
Edwin C. Constable, Catherine E. Housecroft, Markus Neuburger, Sebastien Reymann, Sylvia Schaffner
2004-03-29
Communication
DOI: 10.1039/B402376E
Template synthesis of multi-macrocycles by metathesis reaction‡
Myroslav O. Vysotsky, Anca Bogdan, Leyong Wang, Volker Böhmer
2004-04-28
Communication
DOI: 10.1039/B402719A
A novel 2D net-like supramolecular polymer constructed from Ln6Cu24 node and trans-Cu(Gly)2 bridge
Jian-Jun Zhang, Sheng-Qing Xia, Tian-Lu Sheng, Sheng-Min Hu, Guido Leibeling, Franc Meyer, Xin-Tao Wu, Sheng-Chang Xiang, Rui-Biao Fu
2004-04-14
Communication
DOI: 10.1039/B400447G
H2–O2 atmosphere increases the activity of Pt/TiO2 for benzene photocatalytic oxidation by two orders of magnitude
Yilin Chen, Danzhen Li, Xinchen Wang, Xuxu Wang, Xianzhi Fu
2004-09-02
Communication
DOI: 10.1039/B408187K
Fe–Ce–ZSM-5 a new catalyst of outstanding properties in the selective catalytic reduction of NO with NH3
G. Carja, G. Delahay, C. Signorile, B. Coq
2004-05-17
Communication
DOI: 10.1039/B402660H
Thin Pd membrane prepared on macroporous stainless steel tube filter by an in-situ multi-dimensional plating mechanism
Jianhua Tong, Yasuyuki Matsumura
2004-09-20
Communication
DOI: 10.1039/B406975G
Reactions of N-heterocyclic carbenes (NHCs) with one-electron oxidants: possible formation of a carbenecation radical
Taramatee Ramnial, Iain McKenzie, Brian Gorodetsky, Emily M. W. Tsang, Jason A. C. Clyburne
2004-04-01
Communication
DOI: 10.1039/B314110A
Mechanistic and stereochemical aspects of the asymmetric cyclocarbonylation of 1,6-enynes with rhodium catalysts
Thomas M. Schmid, Giambattista Consiglio
2004-09-06
Communication
DOI: 10.1039/B407843H
Effective stabilisation of α-helical structures in short peptides with acetylenic cross-linking agents
Kazuhisa Fujimoto, Natsuko Oimoto, Kahori Katsuno, Masahiko Inouye
2004-05-10
Communication
DOI: 10.1039/B403615H
Poly(vinyl alcohol) star polymers prepared via MADIX/RAFT polymerisation
Martina H. Stenzel, Thomas P. Davis, Christopher Barner-Kowollik
2004-06-02
Communication
DOI: 10.1039/B404763J
You might also like
Compound Q&A
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
1254120-14-32-Methyl-2-propanyl ...
Compound Q&A
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
121202-20-8[2-(3-Chlorophenyl)-...
Compound Q&A
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
42865-19-01-Bromo-2-isocyanato...
Compound Q&A
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
147065-06-34-Nitro-D-phenylalan...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(3beta,22E)-Stigmasta-5,22-dien-3-yl beta-D-glucopyranoside
CAS Number:
19716-26-8
Molecular Formula:
C35H58O6
N-(2,6-Dimethylphenyl)-2-methoxy-N-(2-oxo-1,3-oxazolidin-3-yl)acetamide
CAS Number:
77732-09-3
Molecular Formula:
C14H18N2O4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.