A novel 2D net-like supramolecular polymer constructed from Ln6Cu24 node and trans-Cu(Gly)2 bridge

Literature Information

Publication Date 2004-04-14
DOI 10.1039/B400447G
Impact Factor 6.222
Authors

Jian-Jun Zhang, Sheng-Qing Xia, Tian-Lu Sheng, Sheng-Min Hu, Guido Leibeling, Franc Meyer, Xin-Tao Wu, Sheng-Chang Xiang, Rui-Biao Fu


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Abstract

A 2D net-like lanthanide-copper heterometallic supramolecular network {Ln6Cu27} 1 was synthesized with Ln6Cu24 octahedral cluster as the node and trans-Cu(glycinato)2 group as the linker. The compound represents the first example of 2D polymer with high-nuclear 3d–4f heterometallic cluster as the node.

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