Effective N2 capture by aryl cations at ambient temperature and pressure

Literature Information

Publication Date 2021-04-16
DOI 10.1039/D1CP00903F
Impact Factor 3.676
Authors

Xia Xu, Jianxiong Dai, Xing Guo, Cheng Qian, Pei Zhang, Yixiang Duan, Yonghui Tian


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Abstract

Here, we show that molecular N2 was efficiently captured by organic arylium cations in a well-defined manner at ambient pressure and temperature, which was monitored by on-line mass spectrometry analysis. A kinetic picture was proposed to disclose the principle of the ion–molecule reaction behavior for exclusive aryldiazonium production. The observation has an implication for direct nitrogen fixation into an organic framework via the intermediacy of such cationic species.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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