Effective N2 capture by aryl cations at ambient temperature and pressure
Literature Information
Xia Xu, Jianxiong Dai, Xing Guo, Cheng Qian, Pei Zhang, Yixiang Duan, Yonghui Tian
Here, we show that molecular N2 was efficiently captured by organic arylium cations in a well-defined manner at ambient pressure and temperature, which was monitored by on-line mass spectrometry analysis. A kinetic picture was proposed to disclose the principle of the ion–molecule reaction behavior for exclusive aryldiazonium production. The observation has an implication for direct nitrogen fixation into an organic framework via the intermediacy of such cationic species.
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