A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

Literature Information

Publication Date 2004-04-27
DOI 10.1039/B401301H
Impact Factor 6.222
Authors

Cristina Carcedo, Athanasia Dervisi, Ian A. Fallis, Liling Ooi, K. M. Abdul Malik


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Abstract

The synthesis of the novel C2-symmetric diphosphine 1,4:3,6-dianhydro-2,5-bis(diphenylphosphino)-D-mannitol (ddppm) from D-isomannide is reported and its performance in asymmetric hydrogenations discussed.

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