Intrinsic chemistry of [OUCH]+: reactions with H2O, CH3CN and O2
Literature Information
Luke J. Metzler, Christopher T. Farmen, Theodore A. Corcovilos, Michael J. Van Stipdonk
We report the first experimental study of the intrinsic chemistry of a U-methylidyne species, focusing on reaction of [OUCH]+ with H2O, O2 and CH3CN in the gas phase. DFT was also used to determine reaction pathways, and establish the mechanism by which [OUCH]+ is formed through collision-induced dissociation of [UO2(CCH)]+.
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