Catalytic conversion of fructose into 5-HMF under eco-friendly-biphasic process
Literature Information
Panya Maneechakr, Surachai Karnjanakom
One-pot conversion of fructose into valuable 5-hydroxymethyl-2-furaldehyde (5-HMF) was investigated under a deep eutectic solvent-biphasic system. The role of ChCl, as an inexpensive and safe quaternary ammonium salt, was clearly found to be significant in the reaction. It improved the yield of 5-HMF from fructose dehydration and suppressed the side reactions as well. In addition, the deep eutectic solvent system exhibited a good recyclability with only a small decrease in the 5-HMF yield, while ChCl could be easily recrystallized in the presence of acetonitrile (ACN) (for 5 cycles) or tetrahydrofuran (THF) (for 2 cycles). This research provides a green way for the 5-HMF production via a reusable-biphasic process.
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Reaction Chemistry & Engineering

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.




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