Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway
Literature Information
Franck Paté, Hélène Gérard, Hassan Oulyadi, Aurélien de la Lande, Anne Harrison-Marchand, Olivier Parisel, Jacques Maddaluno
The exchange of Me6Li aggregated to a lithium amide by 7LiCl leads to a specific isotope distribution whose microscopic origin is assigned to an edge-to-edge interaction between the R2NLi–MeLi aggregate and (LiCl)2 by NMR and Car–Parrinello molecular dynamics.
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DOI: 10.1039/AN939640077B
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Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














