Carbon material-supported Fe7C3@FeO nanoparticles: a highly efficient catalyst for carbon dioxide reduction with 1-butene
Literature Information
Publication Date
2020-09-02
DOI
10.1039/D0RE00249F
Impact Factor
4.239
Authors
Bing Yan, Luyi Wang, Bolong Wang, Quanxin Chen, Chunjing Liu, Jian Li, Tao Jiang
View Original
Abstract
The reaction of carbon dioxide reduction with 1-butene to obtain CO and 1,3-butadiene (BD) is of great importance, but is challenging, especially achieving a highly selective transformation to BD. Herein, we conducted the first synthesis of Fe7C3@FeO nanoparticles supported on activated carbon (AC) which contained acid sites rather than Brønsted acids for carbon dioxide reduction with 1-butene. It was found that this material was very efficient for the reaction; in particular, the BD selectivity could be improved up to 54%. In addition, the effects of the carbon surface chemistry on the catalyst composition, structure and morphology as well as its catalytic properties were investigated. Furthermore, the surface oxygen-containing groups over AC, which provided acid sites, were proved to have played a key role in anchoring and dispersing Fe7C3@FeO nanoparticles, which result in the unique catalytic performance of this material.
Recommended Journals
Related Literature
On the position of the potential wall in DFT temporary anion calculations
Nick Sablon, Frank De Proft, Paul Geerlings, David J. Tozer
2007-09-24
Paper
DOI: 10.1039/B711428A
Silica-supported chromium oxide: colloids as building blocks‡
Ive Hermans, Eric Breynaert, Hilde Poelman, Roger De Gryse, Duoduo Liang, Gustaaf Van Tendeloo, André Maes, Jozef Peeters, Pierre Jacobs
2007-08-09
Paper
DOI: 10.1039/B706601E
Conductivity dispersion in supercooled calcium potassium nitrate: caged ionic motion viewed as part of standard behaviour
Klaus Funke, Prabhakar Singh, Radha Dilip Banhatti
2007-10-01
Paper
DOI: 10.1039/B618788A
Dissociative electron attachment to gas phase glycine: Exploring the decomposition pathways by mass separation of isobaric fragment anions
A. Mauracher, S. Denifl, A. Aleem, N. Wendt, F. Zappa, P. Cicman, M. Probst, T. D. Märk, P. Scheier, H. D. Flosadóttir, O. Ingólfsson, E. Illenberger
2007-09-07
Paper
DOI: 10.1039/B709140K
Structures and energetics of 98 atom Pd–Pt nanoalloys: potential stability of the Leary tetrahedron for bimetallic nanoparticles
Lauro Oliver Paz-Borbón, Thomas V. Mortimer-Jones, Roy L. Johnston, Alvaro Posada-Amarillas, Giovanni Barcaro, Alessandro Fortunelli
2007-07-17
Paper
DOI: 10.1039/B707136A
Selected ion flow tube cation–molecule reaction studies and threshold photoelectron photoion coincidence spectroscopy of cyclic-C5F8
Michael A. Parkes, Sahangir Ali, Richard P. Tuckett, Victor A. Mikhailov, Chris A. Mayhew
2007-08-02
Paper
DOI: 10.1039/B704862A
Potential energy surface for cyclotrimethylene trinitramine dimer from symmetry-adapted perturbation theory‡
Robert Bukowski, Betsy M. Rice
2007-08-23
Paper
DOI: 10.1039/B709192C
Constraints at the transition state of the D + H2 reaction: quantum bottlenecks vs. stereodynamics
F. J. Aoiz, V. J. Herrero, M. P. de Miranda, V. Sáez Rábanos
2007-08-14
Paper
DOI: 10.1039/B709161C
Probing the evaporation of ternary ethanol–methanol–water droplets by cavity enhanced Raman scattering
Chris R. Howle, Chris J. Homer, Rebecca J. Hopkins, Jonathan P. Reid
2007-08-06
Paper
DOI: 10.1039/B706211G
You might also like
Compound Q&A
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
858-46-82,4,6-Tris(pentafluo...
Compound Q&A
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
56787-36-1Chloroac-nle-oh
Compound Q&A
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
55095-15-3alpha-(2-Bromophenyl...
Compound Q&A
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
139585-48-12-Chloro-5-methoxypy...
Compound Q&A
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
12036-22-5Tungsten(IV) oxide
Source Journal
Reaction Chemistry & Engineering
CiteScore:
0
Self-citation Rate:
8.8%
Articles per Year:
284
Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.
Recommended Compounds
![1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure](https://static.chemtradehub.com/structs/192/19210-12-9-ecae.webp "1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure")
1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate
CAS Number:
19210-12-9
Molecular Formula:
C24H30O11
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.