Ni-Catalyzed asymmetric hetero-Diels–Alder reactions of conjugated vinyl azides: synthesis of chiral azido polycycles
Literature Information
Shunian Li, Haifeng Lu, Fang Wei
We report herein an efficient Ni(II)/Feng ligand-catalyzed asymmetric hetero-Diels–Alder reaction between conjugated vinyl azides and carbonyl groups. This method provides a platform for the synthesis of complicated chiral azido polycycles in high yields and excellent enantioselectivities.
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Organic Chemistry Frontiers

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry














