Rh(iii)-Catalyzed sulfonylamination of α-indolyl alcohols via Csp2–Csp3 bond cleavage
Literature Information
Publication Date
2020-12-30
DOI
10.1039/D0QO01426E
Impact Factor
5.281
Authors
Xinwei Hu, Zheng Tan, Zhipeng Liu, Fengjuan Chen, Huanfeng Jiang, Wei Zeng
View Original
Abstract
A Rh(III)-catalyzed beta-carbon amination of α-aryl alcohols with sulfonyl azides has been developed. This transformation features unstrained Csp2–Csp3 σ bond amination via C–C σ bond cleavage, and provides a direct approach to complex 2-aminoindoles.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate
CAS Number:
19210-12-9
Molecular Formula:
C24H30O11
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