Dependence of the nascent vibrational distribution of NO(v) on the photolysis wavelength of NO2 in the range λ = 266–327 nm measured by time-resolved Fourier transform infrared emission
Literature Information
C. Brooks, G. Hancock, M. Saunders
Time-resolved FTIR has been used to study the photodissociation of NO2 at photolysis wavelengths of λ = 266, 282, 295, 308, 320 and 327 nm. Nascent vibrational distributions of the NO(v) fragment have been determined at all wavelengths: 266 nm photolysis populates NO(v = 1–7) and shows a distribution that is inverted at v = 5, whereas 327 nm photolysis populates NO(v = 1–3) and is inverted at v = 2. Surprisal plots were performed on the nascent distributions presented in this work and on all data sets available in the literature in the range 266–370 nm in order to parameterise the wavelength dependence of the nascent distribution of NO(v) from NO2 photolysis. In general, the surprisal parameter was found to be a linear function of wavelength and was used to generate a simple model for the wavelength dependence of the nascent distribution of NO(v) in the region λ = 265–372.5 nm. The results give a more accurate parameterisation of the formation of NO(v) of use in atmospheric modelling.
Recommended Journals

Bioorganic & Medicinal Chemistry Letters

Heteroatom Chemistry

NDT & E International

Journal of Chemical Sciences

Critical Reviews in Solid State and Materials Sciences

Medicinal Chemistry Research

Polycyclic Aromatic Compounds

Journal of Asian Natural Products Research

Cellulose

Bioorganic & Medicinal Chemistry
Related Literature
Kinetic analysis of supported Ni-catalyzed CO2/CH4 reactions using photoacoustic spectroscopy
Ji-Woong Kim, Jae-Au Ha, Hun Jung, Byung-II Ahn, Sung-Han Lee, Joong-Gill Choi
DOI: 10.1039/B709102H
Multiphoton dissociation dynamics of BrCl and the BrCl+cation
Olivier P. J. Vieuxmaire, N. Hendrik Nahler, Richard N. Dixon, Michael N. R. Ashfold
DOI: 10.1039/B709222A
Coverage dependent structures of oligopyridine adlayers on (111) oriented Ag films
Matthias Roos, Harry E. Hoster, Achim Breitruck, R. Jürgen Behm
DOI: 10.1039/B708578H
Potential energy surface for cyclotrimethylene trinitramine dimer from symmetry-adapted perturbation theory‡
Robert Bukowski, Betsy M. Rice
DOI: 10.1039/B709192C
A coupled cluster study of the electronic spectroscopy and photochemistry of Cr(CO)6
Sébastien Villaume, Alain Strich, Chantal Daniel, S. Ajith Perera, Rodney J. Bartlett
DOI: 10.1039/B709050A
Global exploration of the energy landscape of solids on the ab initio level
K. Doll, J. C. Schön, M. Jansen
DOI: 10.1039/B709943F
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




