2-Methyl-2-propanyl (3R,5S)-6-chloro-3,5-dihydroxyhexanoate
CAS Number:
154026-93-4
Molecular Formula:
C10H19ClO4
Access to SCN-containing thiazolines via electrochemical regioselective thiocyanothiocyclization of N-allylthioamides
Literature Information
Publication Date
2020-04-09
DOI
10.1039/D0QO00300J
Impact Factor
5.281
Authors
Yan-An Zhang, Zhong Ding, Peng Liu, Wei-Si Guo, Li-Rong Wen, Ming Li
View Original
Abstract
An electrochemical thiocyanothiocyclization of N-allylthioamides has been developed for the synthesis of SCN-containing 2-thiazolines. This method provides a green and efficient approach to generate 5-exo-cyclization 2-thiazolines with a broad substrate scope and good yields. In addition, 6-endo-cyclization isothiocyanato thiazines are formed regioselectively when cyclic thioamides are used as reactants. The reaction is easy to proceed under catalyst-, additive- and oxidant-free conditions.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine structure](https://static.chemtradehub.com/structs/201/201484-50-6-c2fc.webp "N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine structure")
N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine
CAS Number:
201484-50-6
Molecular Formula:
C30H25NO4
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