Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water
Literature Information
Publication Date
2020-09-28
DOI
10.1039/D0PY00994F
Impact Factor
5.582
Authors
Shan-Qing Peng, Butian Zhang, Wenhao Fan, Shuifeng Wang, Zhi-Hao Zhang, Yan Liu, Shi-Lu Chen, Mu-Hua Huang
View Original
Abstract
This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-para-nitrophenylether of the norbornene diol. The polymerization rate of exo-NBNPE (kapp = 18.7 × 10−2 s−1) is faster than that of endo-NBNPE (kapp = 3.64 × 10−2 s−1). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate
CAS Number:
587-98-4
Molecular Formula:
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