Rh(i)-Catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes with the N-terminal of the diazo group
Literature Information
Publication Date
2019-05-08
DOI
10.1039/C9QO00403C
Impact Factor
5.281
Authors
Bo Wang, Yuankai Wang, Zixuan Wang
View Original
Abstract
A new type of Rh(I)-catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes and the N-terminal of a diazo moiety is reported. This study is the first attempt to combine oxidative cyclometallation with carbene migratory insertion. This reaction is suggested to involve the initial oxidative cyclometallation, followed by migratory nitrogen insertion and reductive elimination.
Recommended Journals
Bioorganic & Medicinal Chemistry Letters
Journal of the Indian Institute of Science
Critical Reviews in Solid State and Materials Sciences
Heteroatom Chemistry
Topics in Catalysis
Chinese Journal of Chemistry
Main Group Chemistry
Acta Metallurgica Sinica-English Letters
Herald of the Russian Academy of Sciences
Cellulose
Related Literature
Synthetic and mechanistic inputs of photochemistry into the bis-acetylacetonatocobalt-mediated radical polymerization of n-butyl acrylate and vinyl acetate
Christophe Detrembleur, Yasmine Piette, Marie Hurtgen, Christine Jérôme, Jacques Lalevée, Antoine Debuigne
2011-11-28
Paper
DOI: 10.1039/C1PY00443C
Double click reaction strategies for polymer conjugation and post-functionalization of polymers
Hakan Durmaz, Amitav Sanyal, Gurkan Hizal, Umit Tunca
2011-12-02
Review Article
DOI: 10.1039/C1PY00471A
Functional conjugated microporous polymers: from 1,3,5-benzene to 1,3,5-triazine
Shijie Ren, Robert Dawson, Andrea Laybourn, Jia-xing Jiang, Yaroslav Khimyak, Dave J. Adams, Andrew I. Cooper
2012-01-30
Paper
DOI: 10.1039/C2PY00585A
Metal-free click polymerization of propiolates and azides: facile synthesis of functional poly(aroxycarbonyltriazole)s
Hongkun Li, Jian Wang, Jing Zhi Sun, Rongrong Hu, Anjun Qin
2012-02-17
Paper
DOI: 10.1039/C2PY00586G
Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity
Radovan Vukićević, Ivana Vukovic, Hristiyan Stoyanov, Andreas Korwitz, Doris Pospiech, Guggi Kofod, Katja Loos, Gerrit ten Brinke, Sabine Beuermann
2012-05-16
Paper
DOI: 10.1039/C2PY20166F
A new polyfluorene bearing pyridine moieties: a sensitive fluorescent chemosensor for metal ions and cyanide
Xiaoding Lou, Yi Zhang, Shuang Li, Daxin Ou, Zhaomin Wan, Jingui Qin, Zhen Li
2012-04-03
Paper
DOI: 10.1039/C2PY20022H
Heteronucleobase-functionalized benzoxazine: synthesis, thermal properties, and self-assembled structure formed through multiple hydrogen bonding interactions
Wei-Hsun Hu, Kai-Wei Huang, Shiao-Wei Kuo
2012-04-13
Paper
DOI: 10.1039/C2PY20090B
Substituent effects on the stabilities of polymeric and small molecule bis-terpyridine complexes
Ian M. Henderson, Ryan C. Hayward
2012-03-13
Paper
DOI: 10.1039/C2PY20042B
A new story of cyclodextrin as a bulky pendent group causing uncommon behaviour to random copolymers in solution
Fuji Sakai, Guosong Chen, Ming Jiang
2012-01-31
Paper
DOI: 10.1039/C2PY00614F
You might also like
Compound Q&A
Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?
When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...
3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A
How should (1R,9S,10S,12S,14E,16S,19R,20R,21S,22R)-3,9,21-Trihydroxy-5,10,12,14,16,20,22-heptamethyl-23,24-dioxatetracyclo[17.3.1.1~6,9~.0~2,7~]tetracosa-2,5,7,14-tetraen-4-one (CAS: 183202-73-5) be stored?
This compound should be stored in a cool, dry place away from direct sunlight. I...
183202-73-5(1R,9S,10S,12S,14E,1...
Compound Q&A
How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?
3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...
419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A
How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?
5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...
1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A
What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?
2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...
1206978-15-52-Chloro-4-(difluoro...
Compound Q&A
What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?
3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...
1121-79-53-Chloro-6-methylpyr...
Compound Q&A
Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?
Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...
90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A
Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?
Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...
63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A
What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?
3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...
1261906-29-93-Amino-5-chloropyri...
Compound Q&A
What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?
When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...
1092349-93-36,7-Difluoro-2,3-dih...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
tert-Butyl 4-(2-(p-Tolylsulfonyl)hydrazono)piperidine-1-carboxylate
CAS Number:
1046478-89-0
Molecular Formula:
C17H25N3O4S
5-(3,4-Dimethoxybenzyl)-2,4-pyrimidinediamine hydrochloride (1:1)
CAS Number:
2507-23-5
Molecular Formula:
C13H17ClN4O2
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.