tert-Butyl 4-(2-(p-Tolylsulfonyl)hydrazono)piperidine-1-carboxylate
CAS Number:
1046478-89-0
Molecular Formula:
C17H25N3O4S
Multifunctionalized octamethoxy-[8]cycloparaphenylene: facile synthesis and analysis of novel photophysical and photoinduced electron transfer properties
Literature Information
Publication Date
2019-04-15
DOI
10.1039/C9QO00372J
Impact Factor
5.281
Authors
Shengsheng Cui, Guilin Zhuang, Jinyi Wang, Qiang Huang, Shengda Wang, Pingwu Du
View Original
Abstract
The physical properties of conjugated cycloparaphenylene-based materials highly depend on their sizes, geometries, and functional groups. Herein we reported a facile strategy to synthesize novel multifunctionalized octamethoxy-[8]cycloparaphenylene (OMe-[8]CPP). Remarkably, an unusual hypsochromic shift in the emission spectrum was observed compared to its unfunctionalized nanoring. In addition, the photoinduced electron transfer process between OMe-[8]CPP and a naphthalene diimide electron acceptor is studied for the first time. OMe-[8]CPP will provide a suitable platform for subsequent synthesis manipulations to construct interesting and unprecedented functional nanocarbon structures.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(2R,4R)-1-Boc-4-Aminopyrrolidine-2-carboxylic acid
CAS Number:
132622-98-1
Molecular Formula:
C10H18N2O4
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