Effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior of diazoacetates initiated by π-allylPd complexes
Literature Information
Publication Date
2020-01-22
DOI
10.1039/C9PY01654F
Impact Factor
5.582
Authors
Hiroaki Shimomoto, Moemi Nakajima, Akihiro Watanabe, Hirokazu Murakami, Tomomichi Itoh, Eiji Ihara
View Original
Abstract
In the polymerization of diazoacetates initiated by π-allylPd-based initiating systems, the effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior were investigated. As a result, the polymerization in the presence of pyridine or its derivatives as an additive was found to afford a polymer with relatively narrow molecular weight distribution compared to that with π-allylPdCl alone. Furthermore, we have demonstrated that Pd complexes with π-allyl ligands with a variety of substituents are capable of polymerizing diazoacetates in a similar manner to the parent unsubstituted π-allylPdCl, and the tacticity of the resulting polymers is affected by the structure of the π-allyl ligands.
Related Literature
Understanding the STM images of epitaxial graphene on a reconstructed 6H-SiC(0001) surface: the role of tip-induced mechanical distortion of graphene
Jacques Cousty, Christophe Lubin, François Thoyer
2016-03-07
Paper
DOI: 10.1039/C5CP07571H
Salt effects on the picosecond dynamics of lysozyme hydration water investigated by terahertz time-domain spectroscopy and an insight into the Hofmeister series for protein stability and solubility
Katsuyoshi Aoki, Kentaro Shiraki, Toshiaki Hattori
2016-05-19
Paper
DOI: 10.1039/C5CP06324H
Fragment molecular orbital study of the cAMP-dependent protein kinase catalyzed phosphoryl transfer: a comparison with the differential transition state stabilization method
H. Öberg, T. Brinck
2016-05-12
Paper
DOI: 10.1039/C6CP02623K
Electrochemical interfacial influences on deoxygenation and hydrogenation reactions in CO reduction on a Cu(100) surface
Tian Sheng, Wen-Feng Lin, Shi-Gang Sun
2016-05-11
Paper
DOI: 10.1039/C6CP02198K
Molten fatty acid based microemulsions
Cecile Noirjean, Fabienne Testard, Christophe Dejugnat, Jacques Jestin, David Carriere
2016-05-17
Paper
DOI: 10.1039/C6CP00533K
A simultaneous one pot synthesis of two fractal structures via swapping two fractal reaction kinetic states
Mrinal Dutta, Kanad Ray, Daisuke Fujita, Anirban Bandyopadhyay
2016-04-27
Communication
DOI: 10.1039/C6CP00447D
Prediction of the electronic structure of single-walled black phosphorus nanotubes
Lixiu Guan, Guifeng Chen, Junguang Tao
2016-05-06
Paper
DOI: 10.1039/C6CP01803C
Halogenated earth abundant metalloporphyrins as photostable sensitizers for visible-light-driven water oxidation in a neutral phosphate buffer solution
Hung-Cheng Chen, Joost N. H. Reek, René M. Williams, Albert M. Brouwer
2016-05-10
Paper
DOI: 10.1039/C6CP01352J
Structural investigations on a linear isolated depsipeptide: the importance of dispersion interactions
A. Stamm, D. Bernhard, M. Gerhards
2016-05-05
Paper
DOI: 10.1039/C6CP01675H
You might also like
Compound Q&A
Is 4-Benzyl-2,2-dimethylmorpholine (CAS: 84761-04-6) safe?
4-Benzyl-2,2-dimethylmorpholine is generally considered safe when handled under ...
84761-04-64-Benzyl-2,2-dimethy...
Compound Q&A
What is (5,6-Dimethoxy-3-pyridinyl)boronic acid (CAS: 1346526-61-1)?
(5,6-Dimethoxy-3-pyridinyl)boronic acid is a chemical compound with the molecula...
1346526-61-1(5,6-Dimethoxy-3-pyr...
Compound Q&A
How is 1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane (CAS: 67875-55-2) typically synthesized?
1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane is synthesized throug...
67875-55-21,1,3,3-Tetramethyl-...
Compound Q&A
What are the main uses of (2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid (CAS: 1018818-04-6)?
(2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid is primarily used as a build...
1018818-04-6(2R,4S)-1-Boc-4-meth...
Compound Q&A
What precautions should be taken when handling 2,3-Dichloroacrylonitrile (CAS: 22410-58-8)?
When handling 2,3-Dichloroacrylonitrile, it is crucial to wear appropriate perso...
22410-58-82,3-Dichloroacryloni...
Compound Q&A
How should (S)-1-(o-Tolyl)ethanamine hydrochloride (CAS: 1332832-16-2) be stored?
(S)-1-(o-Tolyl)ethanamine hydrochloride should be stored in a cool, dry place to...
1332832-16-2(S)-1-(o-Tolyl)ethan...
Compound Q&A
What are the physical and chemical properties of Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8)?
Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8...
518047-98-8Benzyl [1-(hydroxyam...
Compound Q&A
What industries use 2-Methyloxazole-5-carbaldehyde (CAS: 885273-42-7)?
2-Methyloxazole-5-carbaldehyde is used in the pharmaceutical industry for the sy...
885273-42-72-Methyloxazole-5-ca...
Compound Q&A
What is the market or research trend for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxylate (CAS: 389889-82-1)?
The market for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxyla...
389889-82-12-Methyl-2-propanyl ...
Compound Q&A
Is 1-Butyl-3-methylpyridinium bromide (CAS: 26576-85-2) safe?
1-Butyl-3-methylpyridinium bromide is generally considered safe for laboratory u...
26576-85-21-Butyl-3-methylpyri...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![3-({2-[(2R,4S)-4-Fluoro-2-methyl-1-pyrrolidinyl]-2-oxoethyl}amino)-3-methyl-1-(1-pyrrolidinyl)-1-butanone structure](https://static.chemtradehub.com/structs/118/1186426-66-3-b2e9.webp "3-({2-[(2R,4S)-4-Fluoro-2-methyl-1-pyrrolidinyl]-2-oxoethyl}amino)-3-methyl-1-(1-pyrrolidinyl)-1-butanone structure")
3-({2-[(2R,4S)-4-Fluoro-2-methyl-1-pyrrolidinyl]-2-oxoethyl}amino)-3-methyl-1-(1-pyrrolidinyl)-1-butanone
CAS Number:
1186426-66-3
Molecular Formula:
C16H28FN3O2
![3-(6-Nitrobenzo[d][1,3]dioxol-5-yl)acrylic acid structure](https://static.chemtradehub.com/structs/631/6315-90-8-6b36.webp "3-(6-Nitrobenzo[d][1,3]dioxol-5-yl)acrylic acid structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.